σ- and π-aryl nitrenium ions

Paul Haberfield, Michael De Rosa

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

It is suggested that N-acyl-N-acetoxyarylamines solvolyse readily via a π-nitrenium ion, whereas N-alkyl-N-acetoxyarylamines, which would have to react via a σ-nitrenium ion, are stable to solvolysis.

Original languageEnglish (US)
Pages (from-to)1716-1717
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
StatePublished - Jan 1 1985

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All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

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title = "σ- and π-aryl nitrenium ions",
abstract = "It is suggested that N-acyl-N-acetoxyarylamines solvolyse readily via a π-nitrenium ion, whereas N-alkyl-N-acetoxyarylamines, which would have to react via a σ-nitrenium ion, are stable to solvolysis.",
author = "Paul Haberfield and {De Rosa}, Michael",
year = "1985",
month = "1",
day = "1",
doi = "10.1039/C39850001716",
language = "English (US)",
pages = "1716--1717",
journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
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}

σ- and π-aryl nitrenium ions. / Haberfield, Paul; De Rosa, Michael.

In: Journal of the Chemical Society, Chemical Communications, No. 23, 01.01.1985, p. 1716-1717.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Haberfield, Paul

AU - De Rosa, Michael

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AB - It is suggested that N-acyl-N-acetoxyarylamines solvolyse readily via a π-nitrenium ion, whereas N-alkyl-N-acetoxyarylamines, which would have to react via a σ-nitrenium ion, are stable to solvolysis.

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