(2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato) iron(III)

Nan Xu, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN4O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.

Original languageEnglish (US)
Pages (from-to)m1366
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number11
DOIs
StatePublished - 2008

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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