4-MCHM sorption to and desorption from granular activated carbon and raw coal

T. Scott Jeter, Emily A. Sarver, Harold M. McNair, Mohammad Rezaee

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

4-Methylcyclohexanemethanol (4-MCHM) is a saturated higher alicyclic primary alcohol that is used in the froth flotation process for cleaning coal. In early 2014, a large spill of crude chemical (containing primarily 4-MCHM) to the Elk River near Charleston, WV contaminated the local water supply. Carbon filters at the affected water treatment facility quickly became saturated, and the contaminated water was distributed to nearby homes and businesses. Sorption of 4-MCHM to granular activated carbon (GAC) was studied in the laboratory using head space (HS) analysis via gas chromatography with a flame ionization detector (GC-FID). Sorption to raw coal was also investigated, since this material may be of interest as a sorbent in the case of an on-site spill. As expected, sorption to both materials increased with decreased particle size and with increased exposure time; although exposure time proved to be much more important in the case of GAC than for coal. Under similar conditions, GAC sorbed more 4-MCHM than raw coal (e.g., 84.9 vs. 63.1 mg/g, respectively, for 20 × 30 mesh particles exposed to 860 mg/L 4-MCHM solution for 24 h). Desorption from both materials was additionally evaluated. Interestingly, desorption of 4-MCHM on a mass per mass basis was also higher for GAC than for raw coal. Overall, results indicated that GAC readily sorbs 4-MCHM but can also readily release a portion of the chemical, whereas coal sorbs somewhat less 4-MCHM but holds it tightly.

Original languageEnglish (US)
Pages (from-to)160-165
Number of pages6
JournalChemosphere
Volume157
DOIs
StatePublished - Aug 1 2016

Fingerprint

Coal
Activated carbon
activated carbon
Sorption
Desorption
desorption
Carbon
sorption
coal
Hazardous materials spills
Froth flotation
Coal preparation
Sorbents
Water treatment
Water supply
Gas chromatography
Ionization
Flame Ionization
Alcohols
Rivers

All Science Journal Classification (ASJC) codes

  • Environmental Engineering
  • Environmental Chemistry
  • Chemistry(all)
  • Pollution
  • Health, Toxicology and Mutagenesis

Cite this

Jeter, T. Scott ; Sarver, Emily A. ; McNair, Harold M. ; Rezaee, Mohammad. / 4-MCHM sorption to and desorption from granular activated carbon and raw coal. In: Chemosphere. 2016 ; Vol. 157. pp. 160-165.
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4-MCHM sorption to and desorption from granular activated carbon and raw coal. / Jeter, T. Scott; Sarver, Emily A.; McNair, Harold M.; Rezaee, Mohammad.

In: Chemosphere, Vol. 157, 01.08.2016, p. 160-165.

Research output: Contribution to journalArticle

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T1 - 4-MCHM sorption to and desorption from granular activated carbon and raw coal

AU - Jeter, T. Scott

AU - Sarver, Emily A.

AU - McNair, Harold M.

AU - Rezaee, Mohammad

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AB - 4-Methylcyclohexanemethanol (4-MCHM) is a saturated higher alicyclic primary alcohol that is used in the froth flotation process for cleaning coal. In early 2014, a large spill of crude chemical (containing primarily 4-MCHM) to the Elk River near Charleston, WV contaminated the local water supply. Carbon filters at the affected water treatment facility quickly became saturated, and the contaminated water was distributed to nearby homes and businesses. Sorption of 4-MCHM to granular activated carbon (GAC) was studied in the laboratory using head space (HS) analysis via gas chromatography with a flame ionization detector (GC-FID). Sorption to raw coal was also investigated, since this material may be of interest as a sorbent in the case of an on-site spill. As expected, sorption to both materials increased with decreased particle size and with increased exposure time; although exposure time proved to be much more important in the case of GAC than for coal. Under similar conditions, GAC sorbed more 4-MCHM than raw coal (e.g., 84.9 vs. 63.1 mg/g, respectively, for 20 × 30 mesh particles exposed to 860 mg/L 4-MCHM solution for 24 h). Desorption from both materials was additionally evaluated. Interestingly, desorption of 4-MCHM on a mass per mass basis was also higher for GAC than for raw coal. Overall, results indicated that GAC readily sorbs 4-MCHM but can also readily release a portion of the chemical, whereas coal sorbs somewhat less 4-MCHM but holds it tightly.

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