[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ4N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)

Nan Xu; Douglas R. Powell; George B. Richter-Addo

doi:10.1107/S1600536811001395

[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ⁴N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)

Nan Xu, Douglas R. Powell, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Fe(CF₃O₃S)(C₄₈H ₃₆N₄O₄)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The Fe^III atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -N_p distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

Original language	English (US)
Pages (from-to)	m268
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	2
DOIs	https://doi.org/10.1107/S1600536811001395
State	Published - Feb 2011

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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@article{477a111110b44e34a46a088fc81997be,

title = "[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ4N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)",

abstract = "The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) {\AA} towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) {\AA} and the Fe -O distance is 2.001 (2) {\AA}.",

author = "Nan Xu and Powell, {Douglas R.} and Richter-Addo, {George B.}",

year = "2011",

month = feb,

doi = "10.1107/S1600536811001395",

language = "English (US)",

volume = "67",

pages = "m268",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - [5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ4N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)

AU - Xu, Nan

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2011/2

Y1 - 2011/2

N2 - The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

AB - The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

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U2 - 10.1107/S1600536811001395

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VL - 67

SP - m268

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

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