[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ4N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)

Nan Xu; Douglas R. Powell; George B. Richter-Addo

doi:10.1107/S1600536811001395

[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ⁴N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)

Nan Xu, Douglas R. Powell, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article

Abstract

The title compound, [Fe(CF₃O₃S)(C₄₈H ₃₆N₄O₄)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The Fe^III atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -N_p distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

Original language	English (US)
Pages (from-to)	m268
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	2
DOIs	https://doi.org/10.1107/S1600536811001395
Publication status	Published - Feb 1 2011

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All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Xu, N., Powell, D. R., & Richter-Addo, G. B. (2011). [5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ⁴N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III). Acta Crystallographica Section E: Structure Reports Online, 67(2), m268. https://doi.org/10.1107/S1600536811001395

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abstract = "The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) {\AA} towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) {\AA} and the Fe -O distance is 2.001 (2) {\AA}.",

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N2 - The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

AB - The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

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10.1107/S1600536811001395