[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphyrinato-κ4N, N′,N″,N‴](trifluoromethanesulfonato-κO)iron(III)

Nan Xu, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, [Fe(CF3O3S)(C48H 36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe -Np distance is 2.044 (2) Å and the Fe -O distance is 2.001 (2) Å.

Original languageEnglish (US)
Pages (from-to)m268
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number2
DOIs
StatePublished - Feb 2011

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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