A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue

Ross J. Davidson, Eric W. Ainscough, Andrew M. Brodie, Mark R. Waterland, Harry R. Allcock, Mark D. Hindenlang, Boujemaa Moubaraki, Keith S. Murray, Keith C. Gordon, Raphael Horvath, Guy N.L. Jameson

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Mössbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.

Original languageEnglish (US)
Pages (from-to)158-161
Number of pages4
JournalInorganic Chemistry Communications
Volume37
DOIs
StatePublished - Oct 24 2013

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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