A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue

Ross J. Davidson; Eric W. Ainscough; Andrew M. Brodie; Mark R. Waterland; Harry R. Allcock; Mark D. Hindenlang; Boujemaa Moubaraki; Keith S. Murray; Keith C. Gordon; Raphael Horvath; Guy N.L. Jameson

doi:10.1016/j.inoche.2013.09.056

A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue

Ross J. Davidson, Eric W. Ainscough, Andrew M. Brodie, Mark R. Waterland, Harry R. Allcock, Mark D. Hindenlang, Boujemaa Moubaraki, Keith S. Murray, Keith C. Gordon, Raphael Horvath, Guy N.L. Jameson

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Mössbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.

Original language	English (US)
Pages (from-to)	158-161
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	37
DOIs	https://doi.org/10.1016/j.inoche.2013.09.056
State	Published - Oct 24 2013

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Davidson, R. J., Ainscough, E. W., Brodie, A. M., Waterland, M. R., Allcock, H. R., Hindenlang, M. D., Moubaraki, B., Murray, K. S., Gordon, K. C., Horvath, R., & Jameson, G. N. L. (2013). A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue. Inorganic Chemistry Communications, 37, 158-161. https://doi.org/10.1016/j.inoche.2013.09.056

Davidson, Ross J. ; Ainscough, Eric W. ; Brodie, Andrew M. ; Waterland, Mark R. ; Allcock, Harry R. ; Hindenlang, Mark D. ; Moubaraki, Boujemaa ; Murray, Keith S. ; Gordon, Keith C. ; Horvath, Raphael ; Jameson, Guy N.L. / A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue. In: Inorganic Chemistry Communications. 2013 ; Vol. 37. pp. 158-161.

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title = "A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue",

abstract = "M{\"o}ssbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.",

author = "Davidson, {Ross J.} and Ainscough, {Eric W.} and Brodie, {Andrew M.} and Waterland, {Mark R.} and Allcock, {Harry R.} and Hindenlang, {Mark D.} and Boujemaa Moubaraki and Murray, {Keith S.} and Gordon, {Keith C.} and Raphael Horvath and Jameson, {Guy N.L.}",

year = "2013",

month = oct,

day = "24",

doi = "10.1016/j.inoche.2013.09.056",

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Davidson, RJ, Ainscough, EW, Brodie, AM, Waterland, MR, Allcock, HR, Hindenlang, MD, Moubaraki, B, Murray, KS, Gordon, KC, Horvath, R & Jameson, GNL 2013, 'A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue', Inorganic Chemistry Communications, vol. 37, pp. 158-161. https://doi.org/10.1016/j.inoche.2013.09.056

A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue. / Davidson, Ross J.; Ainscough, Eric W.; Brodie, Andrew M.; Waterland, Mark R.; Allcock, Harry R.; Hindenlang, Mark D.; Moubaraki, Boujemaa; Murray, Keith S.; Gordon, Keith C.; Horvath, Raphael; Jameson, Guy N.L.

In: Inorganic Chemistry Communications, Vol. 37, 24.10.2013, p. 158-161.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue

AU - Davidson, Ross J.

AU - Ainscough, Eric W.

AU - Brodie, Andrew M.

AU - Waterland, Mark R.

AU - Allcock, Harry R.

AU - Hindenlang, Mark D.

AU - Moubaraki, Boujemaa

AU - Murray, Keith S.

AU - Gordon, Keith C.

AU - Horvath, Raphael

AU - Jameson, Guy N.L.

PY - 2013/10/24

Y1 - 2013/10/24

N2 - Mössbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.

AB - Mössbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.

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DO - 10.1016/j.inoche.2013.09.056

M3 - Article

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SP - 158

EP - 161

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue

Abstract

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