A cross-linked large channel organic coordination solid

Z. Xu, S. Lee, Y. H. Kiang, A. B. Mallik, N. Tsomaia, Karl Todd Mueller

Research output: Contribution to journalArticlepeer-review

50 Scopus citations

Abstract

A template technique is presented as another approach to fully covalent crystalline networks. In this technique, a metal salt is co-crystallized with a mesoscopic organic molecule. In the resultant crystal, metal-ligand coordination bonds force the organic molecules into the desired channel topology. A reactive non-metallic cross-linking agent is then diffused into the channels. The resultant solid is insoluble in all organic solvents tested but retains its channel structure.

Original languageEnglish (US)
Pages (from-to)637-641
Number of pages5
JournalAdvanced Materials
Volume13
Issue number9
DOIs
StatePublished - May 3 2001

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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