A hyperaccumulation pathway to three-dimensional hierarchical porous nanocomposites for highly robust high-power electrodes

Jian Zhu, Yu Shan, Tao Wang, Hongtao Sun, Zipeng Zhao, Lin Mei, Zheng Fan, Zhi Xu, Imran Shakir, Yu Huang, Bingan Lu, Xiangfeng Duan

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

Natural plants consist of a hierarchical architecture featuring an intricate network of highly interconnected struts and channels that not only ensure extraordinary structural stability, but also allow efficient transport of nutrients and electrolytes throughout the entire plants. Here we show that a hyperaccumulation effect can allow efficient enrichment of selected metal ions (for example, Sn2+, Mn2+) in the halophytic plants, which can then be converted into three-dimensional carbon/metal oxide (3DC/MOx) nanocomposites with both the composition and structure hierarchy. The nanocomposites retain the 3D hierarchical porous network structure, with ultrafine MOX nanoparticles uniformly distributed in multi-layers of carbon derived from the cell wall, cytomembrane and tonoplast. It can simultaneously ensure efficient electron and ion transport and help withstand the mechanical stress during the repeated electrochemical cycles, enabling the active material to combine high specific capacities typical of batteries and the cycling stability of supercapacitors.

Original languageEnglish (US)
Article number13432
JournalNature communications
Volume7
DOIs
StatePublished - Nov 17 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

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