A model for the chemical vapor deposition of poly(para-xylylene) (parylene) thin films

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Abstract

A kinetic model is developed for the chemical vapor deposition of poly(para-xylylene), or parylene, thin polymer films. The growth process is modeled as a multistep process that includes physisorption of monomer on the surface and subsequent chemisorption. The chemisorption step is equivalent to a propagation reaction between the monomer and a radical chain end, and each chemisorption produces a new chemisorption site. The sticking coefficient of the monomer as a function of substrate temperature is extracted from the measured data using the model and is determined to be 2.0 × 10-5 at 60 °C, increasing to 1.4 × 10-3 at -60 °C. The heat of physisorption for the monomer is also extracted from the experiment, and the value found (75 kJ/mol) is reasonable when compared to those of other similar molecules. The model fits experimental kinetic data well for a large range of pressures and temperatures, and it should be appropriate for use with all parylene-family polymers.

Original languageEnglish (US)
Pages (from-to)1945-1949
Number of pages5
JournalChemistry of Materials
Volume14
Issue number5
DOIs
StatePublished - Jun 8 2002

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Chemisorption
Chemical vapor deposition
Monomers
Thin films
Physisorption
Kinetics
Polymer films
Polymers
Temperature
Molecules
Substrates
Experiments

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

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abstract = "A kinetic model is developed for the chemical vapor deposition of poly(para-xylylene), or parylene, thin polymer films. The growth process is modeled as a multistep process that includes physisorption of monomer on the surface and subsequent chemisorption. The chemisorption step is equivalent to a propagation reaction between the monomer and a radical chain end, and each chemisorption produces a new chemisorption site. The sticking coefficient of the monomer as a function of substrate temperature is extracted from the measured data using the model and is determined to be 2.0 × 10-5 at 60 °C, increasing to 1.4 × 10-3 at -60 °C. The heat of physisorption for the monomer is also extracted from the experiment, and the value found (75 kJ/mol) is reasonable when compared to those of other similar molecules. The model fits experimental kinetic data well for a large range of pressures and temperatures, and it should be appropriate for use with all parylene-family polymers.",
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A model for the chemical vapor deposition of poly(para-xylylene) (parylene) thin films. / Fortin, Jeffery B.; Lu, T. M.

In: Chemistry of Materials, Vol. 14, No. 5, 08.06.2002, p. 1945-1949.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A model for the chemical vapor deposition of poly(para-xylylene) (parylene) thin films

AU - Fortin, Jeffery B.

AU - Lu, T. M.

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N2 - A kinetic model is developed for the chemical vapor deposition of poly(para-xylylene), or parylene, thin polymer films. The growth process is modeled as a multistep process that includes physisorption of monomer on the surface and subsequent chemisorption. The chemisorption step is equivalent to a propagation reaction between the monomer and a radical chain end, and each chemisorption produces a new chemisorption site. The sticking coefficient of the monomer as a function of substrate temperature is extracted from the measured data using the model and is determined to be 2.0 × 10-5 at 60 °C, increasing to 1.4 × 10-3 at -60 °C. The heat of physisorption for the monomer is also extracted from the experiment, and the value found (75 kJ/mol) is reasonable when compared to those of other similar molecules. The model fits experimental kinetic data well for a large range of pressures and temperatures, and it should be appropriate for use with all parylene-family polymers.

AB - A kinetic model is developed for the chemical vapor deposition of poly(para-xylylene), or parylene, thin polymer films. The growth process is modeled as a multistep process that includes physisorption of monomer on the surface and subsequent chemisorption. The chemisorption step is equivalent to a propagation reaction between the monomer and a radical chain end, and each chemisorption produces a new chemisorption site. The sticking coefficient of the monomer as a function of substrate temperature is extracted from the measured data using the model and is determined to be 2.0 × 10-5 at 60 °C, increasing to 1.4 × 10-3 at -60 °C. The heat of physisorption for the monomer is also extracted from the experiment, and the value found (75 kJ/mol) is reasonable when compared to those of other similar molecules. The model fits experimental kinetic data well for a large range of pressures and temperatures, and it should be appropriate for use with all parylene-family polymers.

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