A molecular dynamics study of thin-film formation via molecular cluster beam deposition: Effect of incident species

Yanhong Hu, Susan B. Sinnott

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Molecular dynamics simulations are used to study thin-film nucleation and growth through the deposition of molecular cluster beams on diamond surfaces. A reactive, empirical bond-order hydrocarbon potential is used to calculate the forces on the atoms. Beams of ethylene (C2H4) molecular clusters, adamantane (C10H16) molecules, and fullerene (C20) molecules are deposited on hydrogen terminated diamond (111) surfaces at room temperature. These three beams are chosen because of the different chemical bonding in the incident particles - van der Waals interactions in the case of the ethylene molecular clusters, pure sp3 bonds in the case of the adamantane molecules, and covalent sp2 bonds with distorted p-orbitals in the case of the fullerene molecules. All three beams are deposited on the surface along either the [1̄1̄2] direction or the [1̄10] direction at incident angles of 0°, 15°, 45° and 60° from the surface normal. Two deposition energies are considered: a total energy of 400 eV/cluster or molecule and a total energy where the momentum normal to the surface is equivalent to an energy of 400 eV/cluster or molecule. The C20 is found to be the most efficient species at producing an amorphous thin film while the molecular cluster beam of ethylene is the least efficient. Despite the differences in the chemical bonding in the three incident species, the structures of the resultant thin films are predicted to be similar at these energies.

Original languageEnglish (US)
Pages (from-to)230-242
Number of pages13
JournalSurface Science
Volume526
Issue number3
DOIs
StatePublished - Mar 1 2003

Fingerprint

molecular clusters
Molecular dynamics
molecular dynamics
Thin films
Molecules
thin films
Adamantane
Fullerenes
molecules
Ethylene
Diamond
ethylene
fullerenes
Diamonds
diamonds
energy
Covalent bonds
covalent bonds
Amorphous films
Hydrocarbons

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

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abstract = "Molecular dynamics simulations are used to study thin-film nucleation and growth through the deposition of molecular cluster beams on diamond surfaces. A reactive, empirical bond-order hydrocarbon potential is used to calculate the forces on the atoms. Beams of ethylene (C2H4) molecular clusters, adamantane (C10H16) molecules, and fullerene (C20) molecules are deposited on hydrogen terminated diamond (111) surfaces at room temperature. These three beams are chosen because of the different chemical bonding in the incident particles - van der Waals interactions in the case of the ethylene molecular clusters, pure sp3 bonds in the case of the adamantane molecules, and covalent sp2 bonds with distorted p-orbitals in the case of the fullerene molecules. All three beams are deposited on the surface along either the [1̄1̄2] direction or the [1̄10] direction at incident angles of 0°, 15°, 45° and 60° from the surface normal. Two deposition energies are considered: a total energy of 400 eV/cluster or molecule and a total energy where the momentum normal to the surface is equivalent to an energy of 400 eV/cluster or molecule. The C20 is found to be the most efficient species at producing an amorphous thin film while the molecular cluster beam of ethylene is the least efficient. Despite the differences in the chemical bonding in the three incident species, the structures of the resultant thin films are predicted to be similar at these energies.",
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A molecular dynamics study of thin-film formation via molecular cluster beam deposition : Effect of incident species. / Hu, Yanhong; Sinnott, Susan B.

In: Surface Science, Vol. 526, No. 3, 01.03.2003, p. 230-242.

Research output: Contribution to journalArticle

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