A New Approach to the Cedrane Ring System via Intramolecular [4 + 2] Tropone-Olefin Cycloaddition. Total Synthesis of (±)-α- and (±)-β-Pipitzol

Raymond Lee Funk, Gary L. Bolton

Research output: Contribution to journalLetter

10 Scopus citations

Abstract

A new strategy for the preparation of poly-carbocyclic natural products is demonstrated by a concise transformation of an intramolecular tropone-olefin cy-cloadduct (3) to the cedrane ring system of the pipitzols (1a, b).

Original languageEnglish (US)
Pages (from-to)3173-3174
Number of pages2
JournalJournal of Organic Chemistry
Volume52
Issue number14
DOIs
StatePublished - Jul 1 1987

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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