Additions and Corrections: Photoinduced Electron Transfer in Covalently Linked Ruthenium Tris(bipyridyl)-Viologen Molecules: Observation of Back Electron Transfer in the Marcus Inverted Region (Journal of the American Chemical Society (1992) 114(32) (8081–8087)(10.1021/ja00047a017))

Edward H. Yonemoto, Richard L. Riley, Yeong Il Kim, Stephen J. Atherton, Russell H. Schmehl, Thomas E. Mallouk

Research output: Contribution to journalComment/debate

7 Citations (Scopus)

Abstract

Due to a programming error, incorrect values of the square of the electronic coupling matrix element, |F(r)|2, were reported in the caption for Figure 4 and in the text on p 8086. The other parameters (S, λ, λS, hv) and fits to the data shown in the figure represent the correct \V(r)\2 values, which are as follows: [formula omitted] The assertion made on p 8086 that electronic coupling for the forward reactions, which occur through a shorter spacer, is significantly stronger than it is for the back reactions should be disregarded in light of the corrected |V(r)|2 values.

Original languageEnglish (US)
Number of pages1
JournalJournal of the American Chemical Society
Volume115
Issue number12
DOIs
StatePublished - Jun 1 1993

Fingerprint

Viologens
2,2'-Dipyridyl
Ruthenium
Observation
Electrons
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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title = "Additions and Corrections: Photoinduced Electron Transfer in Covalently Linked Ruthenium Tris(bipyridyl)-Viologen Molecules: Observation of Back Electron Transfer in the Marcus Inverted Region (Journal of the American Chemical Society (1992) 114(32) (8081–8087)(10.1021/ja00047a017))",
abstract = "Due to a programming error, incorrect values of the square of the electronic coupling matrix element, |F(r)|2, were reported in the caption for Figure 4 and in the text on p 8086. The other parameters (S, λ, λS, hv) and fits to the data shown in the figure represent the correct \V(r)\2 values, which are as follows: [formula omitted] The assertion made on p 8086 that electronic coupling for the forward reactions, which occur through a shorter spacer, is significantly stronger than it is for the back reactions should be disregarded in light of the corrected |V(r)|2 values.",
author = "Yonemoto, {Edward H.} and Riley, {Richard L.} and {Il Kim}, Yeong and Atherton, {Stephen J.} and Schmehl, {Russell H.} and Mallouk, {Thomas E.}",
year = "1993",
month = "6",
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language = "English (US)",
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journal = "Journal of the American Chemical Society",
issn = "0002-7863",
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TY - JOUR

T1 - Additions and Corrections

T2 - Photoinduced Electron Transfer in Covalently Linked Ruthenium Tris(bipyridyl)-Viologen Molecules: Observation of Back Electron Transfer in the Marcus Inverted Region (Journal of the American Chemical Society (1992) 114(32) (8081–8087)(10.1021/ja00047a017))

AU - Yonemoto, Edward H.

AU - Riley, Richard L.

AU - Il Kim, Yeong

AU - Atherton, Stephen J.

AU - Schmehl, Russell H.

AU - Mallouk, Thomas E.

PY - 1993/6/1

Y1 - 1993/6/1

N2 - Due to a programming error, incorrect values of the square of the electronic coupling matrix element, |F(r)|2, were reported in the caption for Figure 4 and in the text on p 8086. The other parameters (S, λ, λS, hv) and fits to the data shown in the figure represent the correct \V(r)\2 values, which are as follows: [formula omitted] The assertion made on p 8086 that electronic coupling for the forward reactions, which occur through a shorter spacer, is significantly stronger than it is for the back reactions should be disregarded in light of the corrected |V(r)|2 values.

AB - Due to a programming error, incorrect values of the square of the electronic coupling matrix element, |F(r)|2, were reported in the caption for Figure 4 and in the text on p 8086. The other parameters (S, λ, λS, hv) and fits to the data shown in the figure represent the correct \V(r)\2 values, which are as follows: [formula omitted] The assertion made on p 8086 that electronic coupling for the forward reactions, which occur through a shorter spacer, is significantly stronger than it is for the back reactions should be disregarded in light of the corrected |V(r)|2 values.

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