Adsorption of pharmaceuticals onto isolated polyamide active layer of NF/RO membranes

Yan ling Liu, Xiao mao Wang, Hong wei Yang, Yuefeng F. Xie

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Adsorption of trace organic compounds (TrOCs) onto the membrane materials has a great impact on their rejection by nanofiltration (NF) and reverse osmosis (RO) membranes. This study aimed to investigate the difference in adsorption of various pharmaceuticals (PhACs) onto different NF/RO membranes and to demonstrate the necessity of isolating the polyamide (PA) active layer from the polysulfone (PS) support layer for adsorption characterization and quantification. Both the isolated PA layers and the PA+PS layers of NF90 and ESPA1 membranes were used to conduct static adsorption tests. Results showed that apparent differences existed between the PA layer and the PA+PS layer in the adsorption capacity of PhACs as well as the time necessary to reach the adsorption equilibrium. PhACs with different physicochemical properties could be adsorbed to different extents by the isolated PA layer, which was mainly attributed to electrostatic attraction/repulsion and hydrophobic interactions. The PA layer of ESPA1 exhibited apparently higher adsorption capacities for the positively charged PhACs and similar adsorption capacities for the neutral PhACs although it had significantly less total interfacial area (per unit membrane surface area) for adsorption compared to the PA layer of NF90. The higher affinity of the PA layer of ESPA1 for the PhACs could be due to its higher capacity of forming hydrogen bonds with PhACs resulted from the modified chemistry with more –OH groups. This study provides a novel approach to determining the TrOC adsorption onto the active layer of membranes for the ease of investigating adsorption mechanisms.

Original languageEnglish (US)
Pages (from-to)36-47
Number of pages12
JournalChemosphere
Volume200
DOIs
StatePublished - Jun 2018

Fingerprint

Osmosis
Osmosis membranes
Nanofiltration
active layer
Nylons
Reverse osmosis
Polyamides
Drug products
Adsorption
drug
membrane
adsorption
Membranes
Pharmaceutical Preparations
Polysulfones
Organic compounds
organic compound
reverse osmosis
physicochemical property
Static Electricity

All Science Journal Classification (ASJC) codes

  • Environmental Engineering
  • Environmental Chemistry
  • Chemistry(all)
  • Pollution
  • Health, Toxicology and Mutagenesis

Cite this

Liu, Yan ling ; Wang, Xiao mao ; Yang, Hong wei ; Xie, Yuefeng F. / Adsorption of pharmaceuticals onto isolated polyamide active layer of NF/RO membranes. In: Chemosphere. 2018 ; Vol. 200. pp. 36-47.
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Adsorption of pharmaceuticals onto isolated polyamide active layer of NF/RO membranes. / Liu, Yan ling; Wang, Xiao mao; Yang, Hong wei; Xie, Yuefeng F.

In: Chemosphere, Vol. 200, 06.2018, p. 36-47.

Research output: Contribution to journalArticle

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AB - Adsorption of trace organic compounds (TrOCs) onto the membrane materials has a great impact on their rejection by nanofiltration (NF) and reverse osmosis (RO) membranes. This study aimed to investigate the difference in adsorption of various pharmaceuticals (PhACs) onto different NF/RO membranes and to demonstrate the necessity of isolating the polyamide (PA) active layer from the polysulfone (PS) support layer for adsorption characterization and quantification. Both the isolated PA layers and the PA+PS layers of NF90 and ESPA1 membranes were used to conduct static adsorption tests. Results showed that apparent differences existed between the PA layer and the PA+PS layer in the adsorption capacity of PhACs as well as the time necessary to reach the adsorption equilibrium. PhACs with different physicochemical properties could be adsorbed to different extents by the isolated PA layer, which was mainly attributed to electrostatic attraction/repulsion and hydrophobic interactions. The PA layer of ESPA1 exhibited apparently higher adsorption capacities for the positively charged PhACs and similar adsorption capacities for the neutral PhACs although it had significantly less total interfacial area (per unit membrane surface area) for adsorption compared to the PA layer of NF90. The higher affinity of the PA layer of ESPA1 for the PhACs could be due to its higher capacity of forming hydrogen bonds with PhACs resulted from the modified chemistry with more –OH groups. This study provides a novel approach to determining the TrOC adsorption onto the active layer of membranes for the ease of investigating adsorption mechanisms.

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