TY - CHAP
T1 - Advances in the synthesis and catalysis of solid and hollow zeolite-encapsulated metal catalysts
AU - Dai, Chengyi
AU - Zhang, Anfeng
AU - Song, Chunshan
AU - Guo, Xinwen
N1 - Funding Information:
The authors thank the financial support from the State Key Program of National Natural Science Foundation of China (21236008), the National Key R&D Program of China (2018YFB0604901), the National Natural Science Foundation of China (21706210), the Special Research Project of Education Department of Shaanxi Provincial Government (17JK0777), the Natural Science Fundamental Research Program of Shaanxi Province (2018JQ2067), and the QianRen Type B Award to C.S. from Chinese government.
Publisher Copyright:
© 2018 Elsevier Inc.
PY - 2018
Y1 - 2018
N2 - Metals and zeolites are two important types of catalysts and widely used in oxidation–reduction and acid-catalyzed reactions, respectively. In recent years, zeolite-encapsulated metal catalysts have attracted great interest due to their excellent performance in metal–acid synergistic catalysis, selectivity to desired product, anti-leaching, and anti-sintering of metal. This review highlights the synthesis strategies for solid and hollow zeolite-encapsulated metal catalysts, such as ion-exchange, “ship-in-a-bottle,” hydrothermal crystallization, dry gel conversion, and posttreatment method, and their activity, selectivity, and stability in different reactions including hydrogenation, oxidation, reforming, coupling, reforming, hydroxylation, and degradation. The synthesis and advantages of hollow zeolite-encapsulated metal catalysts in various reactions are highlighted.
AB - Metals and zeolites are two important types of catalysts and widely used in oxidation–reduction and acid-catalyzed reactions, respectively. In recent years, zeolite-encapsulated metal catalysts have attracted great interest due to their excellent performance in metal–acid synergistic catalysis, selectivity to desired product, anti-leaching, and anti-sintering of metal. This review highlights the synthesis strategies for solid and hollow zeolite-encapsulated metal catalysts, such as ion-exchange, “ship-in-a-bottle,” hydrothermal crystallization, dry gel conversion, and posttreatment method, and their activity, selectivity, and stability in different reactions including hydrogenation, oxidation, reforming, coupling, reforming, hydroxylation, and degradation. The synthesis and advantages of hollow zeolite-encapsulated metal catalysts in various reactions are highlighted.
UR - http://www.scopus.com/inward/record.url?scp=85056317062&partnerID=8YFLogxK
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U2 - 10.1016/bs.acat.2018.10.002
DO - 10.1016/bs.acat.2018.10.002
M3 - Chapter
AN - SCOPUS:85056317062
SN - 9780128150870
T3 - Advances in Catalysis
SP - 75
EP - 115
BT - Advances in Catalysis
A2 - Song, Chunshan
PB - Academic Press Inc.
ER -