TY - JOUR
T1 - AgCl and BiOCl composited with NiFe-LDH for enhanced photo-degradation of Rhodamine B
AU - Huang, Daiqin
AU - Ma, Jianfeng
AU - Yu, Liangmin
AU - Wu, Deren
AU - Wang, Kai
AU - Yang, Meirong
AU - Papoulis, Dimitrios
AU - Komarneni, Sridhar
N1 - Funding Information:
This work was supported by the National Natural Science Foundation of China (Grant No. 21477009 ), the Project of Jiangsu Province Industry-University-Research joint innovation fund ( BY2013024-16 ) and Changzhou Science and Technology Development Program ( CJ20140026 ). The TEM characterization was under the support of Dr. Xiazhang Li.
Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.
PY - 2015/12/17
Y1 - 2015/12/17
N2 - Ni3Fe(OH)80.5CO3·xH2O layered double hydroxide (NiFe-LDH) was used as a precursor to synthesize AgCl-BiOCl-NiFe-LDH composites to extend the light absorption of BiOCl in the visible light region. The synthetic AgCl-BiOCl-NiFe-LDH composites were characterized by XRD, FT-IR and UV-vis Diffuse Reflectance spectroscopy and FE-SEM. The photo-catalytic activity of AgCl-BiOCl-NiFe-LDH composites was evaluated for the decolorization of RhB under the visible light irradiation, which showed that 97.8% of the dye was degraded in 60 min. The photo-catalytic degradation of RhB by AgCl-BiOCl-NiFe-LDH was compared with those by BiOCl-NiFe-LDH and pure BiOCl but the latter two showed lower degradation than the former, which showed the highest activity among the investigated composites. Recycling experiments revealed that AgCl-BiOCl-NiFe-LDH kept very high activity after 4 cycles with an efficiency of 88.6%, which makes it a good candidate for visible-light responsive photo-catalyst with long-term usability.
AB - Ni3Fe(OH)80.5CO3·xH2O layered double hydroxide (NiFe-LDH) was used as a precursor to synthesize AgCl-BiOCl-NiFe-LDH composites to extend the light absorption of BiOCl in the visible light region. The synthetic AgCl-BiOCl-NiFe-LDH composites were characterized by XRD, FT-IR and UV-vis Diffuse Reflectance spectroscopy and FE-SEM. The photo-catalytic activity of AgCl-BiOCl-NiFe-LDH composites was evaluated for the decolorization of RhB under the visible light irradiation, which showed that 97.8% of the dye was degraded in 60 min. The photo-catalytic degradation of RhB by AgCl-BiOCl-NiFe-LDH was compared with those by BiOCl-NiFe-LDH and pure BiOCl but the latter two showed lower degradation than the former, which showed the highest activity among the investigated composites. Recycling experiments revealed that AgCl-BiOCl-NiFe-LDH kept very high activity after 4 cycles with an efficiency of 88.6%, which makes it a good candidate for visible-light responsive photo-catalyst with long-term usability.
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U2 - 10.1016/j.seppur.2015.11.003
DO - 10.1016/j.seppur.2015.11.003
M3 - Article
AN - SCOPUS:84960101259
VL - 156
SP - 789
EP - 794
JO - Separations Technology
JF - Separations Technology
SN - 1383-5866
ER -