Air and water free solid-phase synthesis of thiol stabilized Au nanoparticles with anchored, recyclable dendrimer templates

John D. Gilbertson, Ganesh Vijayaraghavan, Keith J. Stevenson, Bert D. Chandler

Research output: Contribution to journalArticlepeer-review

Abstract

Solid-phase synthetic templates for Au nanoparticles were developed using Merrifield resins and polyamidoamine (PAMAM) dendrimers. This synthetic scheme affords the opportunity to prepare metal nanoparticles in the absence of air and water, and it does not necessitate phase transfer agents that can be difficult to remove in subsequent steps. Amine-terminated generation 5 PAMAM (G5NH 2) dendrimers were grafted to anhydride functionalized polystyrene resin beads and alkylated with 1,2-epoxydodecane to produce G5C12 anCh. The anchored dendrimers bound both Co II and Au III salts from toluene solutions at ratios comparable to those of solution phase alkyl-terminated PAMAM dendrimers. The encapsulated Au III salts could be reduced with NaBH 4 to produce anchored dendrimer encapsulated nanoparticles (DENs). Treatment of the anchored DENs with decanethiol in toluene extracted the Au nanoparticles from the dendrimers as monolayer protected clusters (MPCs). After a brief NaCN etch, the anchored dendrimers were readily recycled and a subsequent synthesis of decanethiol Au MPCs was performed with comparable MPC yield and particle size distribution.

Original languageEnglish (US)
Pages (from-to)11239-11245
Number of pages7
JournalLangmuir
Volume23
Issue number22
DOIs
StatePublished - Oct 23 2007

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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