Alkaline membrane fuel cells with in-situ cross-linked ionomers

Research output: Contribution to journalArticle

26 Scopus citations

Abstract

Improving cell performance and durability through both new materials and membrane electrode processing optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologies. In this work, we adopted an in-situ cross-linking strategy of an anion-conducting block copolymer to prepare durable ionomers for use in alkaline membrane fuel cells (AMFCs). Our goal was to use new ionomers and binders with an aim at improving long-term stability of AMFCs, especially at high operation temperatures. At 80°C, AMFCs with in-situ cross-linked ionomers showed promising stability with an operating life time of more than 350 hours at 100 mA/cm2. We found that the optimized electrode fabrication process and operating conditions can significantly improve the durability performance of AMFCs. For example, a suitable electrode binder in addition to the ion-conducting ionomer can greatly enhance the durability performance of AMFCs. Operating fuel cells under a cathode over-humification condition can also enhance the long-term stability of AMFCs.

Original languageEnglish (US)
Pages (from-to)93-100
Number of pages8
JournalElectrochimica Acta
Volume152
DOIs
StatePublished - Jan 10 2015

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Electrochemistry

Cite this