Alkanesulfonation of Cyclic and High Polymeric Phosphazenes

Harry R. Allcock, Eric H. Klingenberg, Mark F. Welker

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

A method for sulfonating aminophosphazenes with the use of 1,3-propanesultone is described. The alkanesulfonation reactions were first developed with small molecule phosphazene cyclic trimers as models for high polymeric phosphazenes. High molecular weight poly(aminophosphazenes) were then sulfonated using similar techniques. The structure and properties of the alkanesulfonated polymers were examined by DSC, intrinsic viscosity, and 31P, 13C, and 1H NMR spectroscopy. This synthetic approach to sulfonated polymers is valuable for the development of new biomedical materials, membranes, reversibly cross-linkable polymers, surfactants, and polyelectrolytes.

Original languageEnglish (US)
Pages (from-to)5512-5519
Number of pages8
JournalMacromolecules
Volume26
Issue number20
DOIs
StatePublished - Jan 1 1993

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Polymers
Polyelectrolytes
Surface-Active Agents
Nuclear magnetic resonance spectroscopy
Surface active agents
Molecular weight
Viscosity
Membranes
Molecules

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Allcock, Harry R. ; Klingenberg, Eric H. ; Welker, Mark F. / Alkanesulfonation of Cyclic and High Polymeric Phosphazenes. In: Macromolecules. 1993 ; Vol. 26, No. 20. pp. 5512-5519.
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Alkanesulfonation of Cyclic and High Polymeric Phosphazenes. / Allcock, Harry R.; Klingenberg, Eric H.; Welker, Mark F.

In: Macromolecules, Vol. 26, No. 20, 01.01.1993, p. 5512-5519.

Research output: Contribution to journalArticle

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