Alkynyliodonium salts in organic synthesis. Application to the preparation of the tricyclic core of (±)-halichlorine

Ken S. Feldman, Angela L. Perkins, Katherine M. Masters

Research output: Contribution to journalArticlepeer-review

33 Scopus citations

Abstract

The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/ alkylidenecarbene/1,5 C-H insertion sequence that sets the pivotal quaternary center in the target.

Original languageEnglish (US)
Pages (from-to)7928-7932
Number of pages5
JournalJournal of Organic Chemistry
Volume69
Issue number23
DOIs
StatePublished - Nov 12 2004

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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