Amphiphilic poly[bis(trifluoroethoxy)phosphazene]-poly(ethylene oxide block copolymers: Synthesis and micellar characteristics

Youngkyu Chang, Robbyn Prange, Harry R. Allcock, Sang Cheon Lee, Chulhee Kim

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

The micellar characteristics of the amphiphilic diblock copolymers based on a hydrophobic polyphosphazene (PN) and hydrophilic poly(ethylene oxide) (PEO) were investigated by using fluorescence techniques, dynamic light scattering, and transmission electron microscopy. The two diblock copolymers with different ratios of the length of block components form spherical micellar aggregates in an aqueous phase. The critical micelle concentrations of PN-PEO 1 and PN-PEO 2, determined by a fluorescence technique, were 12.4 and 5.2 mg/L, respectively. The mean diameters of the micelles of PN-PEO I and PN-PEO 2, measured by dynamic light scattering, were 100 and 120 nm. The steady-state fluorescence anisotropy values (r) of 1,6-diphenyl-1,3,5-hexatriene (DPH) were 0.103 for PN-PEO 1 and 0.108 for PN-PEO 2. The low anisotropy values for PEO-PN compared to those for other polymeric amphiphiles may be due to the intrinsic flexibility of the trifluoroethoxy-substituted polyphosphazene block, which would allow enhanced rotational diffusion of the probe.

Original languageEnglish (US)
Pages (from-to)8556-8559
Number of pages4
JournalMacromolecules
Volume35
Issue number22
DOIs
StatePublished - Oct 22 2002

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Polyethylene oxides
Block copolymers
Fluorescence
Dynamic light scattering
Anisotropy
Diphenylhexatriene
poly(bis(trifluoroethoxy)phosphazene)
poly(phosphazene)
Amphiphiles
Critical micelle concentration
Micelles
Light transmission
Transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Materials Chemistry

Cite this

Chang, Youngkyu ; Prange, Robbyn ; Allcock, Harry R. ; Lee, Sang Cheon ; Kim, Chulhee. / Amphiphilic poly[bis(trifluoroethoxy)phosphazene]-poly(ethylene oxide block copolymers : Synthesis and micellar characteristics. In: Macromolecules. 2002 ; Vol. 35, No. 22. pp. 8556-8559.
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Amphiphilic poly[bis(trifluoroethoxy)phosphazene]-poly(ethylene oxide block copolymers : Synthesis and micellar characteristics. / Chang, Youngkyu; Prange, Robbyn; Allcock, Harry R.; Lee, Sang Cheon; Kim, Chulhee.

In: Macromolecules, Vol. 35, No. 22, 22.10.2002, p. 8556-8559.

Research output: Contribution to journalArticle

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N2 - The micellar characteristics of the amphiphilic diblock copolymers based on a hydrophobic polyphosphazene (PN) and hydrophilic poly(ethylene oxide) (PEO) were investigated by using fluorescence techniques, dynamic light scattering, and transmission electron microscopy. The two diblock copolymers with different ratios of the length of block components form spherical micellar aggregates in an aqueous phase. The critical micelle concentrations of PN-PEO 1 and PN-PEO 2, determined by a fluorescence technique, were 12.4 and 5.2 mg/L, respectively. The mean diameters of the micelles of PN-PEO I and PN-PEO 2, measured by dynamic light scattering, were 100 and 120 nm. The steady-state fluorescence anisotropy values (r) of 1,6-diphenyl-1,3,5-hexatriene (DPH) were 0.103 for PN-PEO 1 and 0.108 for PN-PEO 2. The low anisotropy values for PEO-PN compared to those for other polymeric amphiphiles may be due to the intrinsic flexibility of the trifluoroethoxy-substituted polyphosphazene block, which would allow enhanced rotational diffusion of the probe.

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