An Atmospheric Constraint on the NO2 Dependence of Daytime Near-Surface Nitrous Acid (HONO)

Sally E. Pusede, Trevor C. VandenBoer, Jennifer G. Murphy, Milos Z. Markovic, Cora J. Young, Patrick R. Veres, James M. Roberts, Rebecca A. Washenfelder, Steven S. Brown, Xinrong Ren, Catalina Tsai, Jochen Stutz, William H. Brune, Eleanor C. Browne, Paul J. Wooldridge, Ashley R. Graham, Robin Weber, Allen H. Goldstein, Sebastien Dusanter, Stephen M. GriffithPhilip S. Stevens, Barry L. Lefer, Ronald C. Cohen

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13 Scopus citations

Abstract

Recent observations suggest a large and unknown daytime source of nitrous acid (HONO) to the atmosphere. Multiple mechanisms have been proposed, many of which involve chemistry that reduces nitrogen dioxide (NO2) on some time scale. To examine the NO2 dependence of the daytime HONO source, we compare weekday and weekend measurements of NO2 and HONO in two U.S. cities. We find that daytime HONO does not increase proportionally to increases in same-day NO2, i.e., the local NO2 concentration at that time and several hours earlier. We discuss various published HONO formation pathways in the context of this constraint.

Original languageEnglish (US)
Pages (from-to)12774-12781
Number of pages8
JournalEnvironmental Science and Technology
Volume49
Issue number21
DOIs
StatePublished - Oct 5 2015

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry

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    Pusede, S. E., VandenBoer, T. C., Murphy, J. G., Markovic, M. Z., Young, C. J., Veres, P. R., Roberts, J. M., Washenfelder, R. A., Brown, S. S., Ren, X., Tsai, C., Stutz, J., Brune, W. H., Browne, E. C., Wooldridge, P. J., Graham, A. R., Weber, R., Goldstein, A. H., Dusanter, S., ... Cohen, R. C. (2015). An Atmospheric Constraint on the NO2 Dependence of Daytime Near-Surface Nitrous Acid (HONO). Environmental Science and Technology, 49(21), 12774-12781. https://doi.org/10.1021/acs.est.5b02511