An Ionophore-Based Anion-Selective Optode Printed on Cellulose Paper

Xuewei Wang, Qi Zhang, Changwoo Nam, Michael Hickner, Mollie Mahoney, Mark E. Meyerhoff

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

A general anion-sensing platform is reported based on a portable and cost-effective ion-selective optode and a smartphone detector equipped with a color analysis app. In contrast to traditional anion-selective optodes using a hydrophobic polymer and/or plasticizer to dissolve hydrophobic sensing elements, the new optode relies on hydrophilic cellulose paper. The anion ionophore and a lipophilic pH indicator are inkjet-printed and adsorbed on paper and form a “dry” hydrophobic sensing layer. Porous cellulose sheets also allow the sensing site to be modified with dried buffer that prevents any sample pH dependence of the observed color change. A highly selective fluoride optode using an AlIII-porphyrin ionophore is examined as an initial example of this new anion sensing platform for measurements of fluoride levels in drinking water samples. Apart from Lewis acid–base recognition, hydrogen bonding recognition is also compatible with this sensing platform.

Original languageEnglish (US)
Pages (from-to)11826-11830
Number of pages5
JournalAngewandte Chemie - International Edition
Volume56
Issue number39
DOIs
StatePublished - 2017

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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