Analysis of Water and Hydroxyl Species in Soda Lime Glass Surfaces Using Attenuated Total Reflection (ATR)-IR Spectroscopy

Shin Ichi Amma, Seong Kim, Carlo G. Pantano

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

ATR-IR spectroscopy is a useful and convenient method for evaluation of local structure and concentration of water and hydroxyl species in glass because it can be more surface sensitive than reflection or transmission IR analysis. In this work, a semiquantitative analysis of the ATR spectra of OH groups and interstitial molecular water species in glass surfaces after various surface treatments is presented. Both hydroxyl groups and interstitial molecular water exist in the hydrated surfaces but the relative water speciation varies with surface treatment. The SiOH and H2O species in the glass surface showed a wide range of hydrogen bonding interactions and their distributions varied with the SO2, polishing, acid leaching, thermal tempering, and chemical strengthening treatments. SIMS analysis of the hydrogen concentration - depth profiles for the acid-leached samples was used to provide independent information to validate and quantify the ATR signal.

Original languageEnglish (US)
Pages (from-to)128-134
Number of pages7
JournalJournal of the American Ceramic Society
Volume99
Issue number1
DOIs
StatePublished - Jan 1 2016

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Lime
Hydroxyl Radical
Infrared spectroscopy
Glass
Water
Surface treatment
Infrared transmission
Acids
Strengthening (metal)
Tempering
Secondary ion mass spectrometry
Polishing
Leaching
Hydrogen
Hydrogen bonds
soda lime

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

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Analysis of Water and Hydroxyl Species in Soda Lime Glass Surfaces Using Attenuated Total Reflection (ATR)-IR Spectroscopy. / Amma, Shin Ichi; Kim, Seong; Pantano, Carlo G.

In: Journal of the American Ceramic Society, Vol. 99, No. 1, 01.01.2016, p. 128-134.

Research output: Contribution to journalArticle

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