Anion photoelectron spectroscopy and density functional investigation of diniobium-carbon clusters

Kenneth Knappenberger, P. A. Clayborne, J. U. Reveles, M. A. Sobhy, C. E. Jones, U. U. Gupta, S. N. Khanna, I. Iordanov, Jorge Osvaldo Sofo, A. W. Castleman

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Experimental photoelectron and computational results show diniobium-carbon (Nb2Cn) clusters to coexist in multiple structural isomers: three-dimensional geometries, planar rings, and linear chains. Threedimensional clusters having up to five carbons are formed preferentially with Nb-Nb bonding, whereas only Nb-C bonding is observed experimentally at six carbons. Clusters consisting of an odd number of atoms are also observed with linear geometries. The larger binary clusters (n ≤ 7) display properties similar to those of pure carbon clusters. We provide evidence for niobium substitution of carbon atoms.

Original languageEnglish (US)
Pages (from-to)319-326
Number of pages8
JournalACS Nano
Volume1
Issue number4
DOIs
StatePublished - Nov 1 2007

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Knappenberger, K., Clayborne, P. A., Reveles, J. U., Sobhy, M. A., Jones, C. E., Gupta, U. U., Khanna, S. N., Iordanov, I., Sofo, J. O., & Castleman, A. W. (2007). Anion photoelectron spectroscopy and density functional investigation of diniobium-carbon clusters. ACS Nano, 1(4), 319-326. https://doi.org/10.1021/nn700167c