Anisotropic Morphological Changes in Goethite during Fe2+-Catalyzed Recrystallization

Prachi Joshi, Christopher A. Gorski

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

When goethite is exposed to aqueous Fe2+, rapid and extensive Fe atom exchange can occur between solid-phase Fe3+ and aqueous Fe2+ in a process referred to as Fe2+-catalyzed recrystallization. This process can lead to the structural incorporation or release of trace elements, which has important implications for contaminant remediation and nutrient biogeochemical cycling. Prior work found that the process did not cause major changes to the goethite structure or morphology. Here, we further investigated if and how goethite morphology and aggregation behavior changed temporally during Fe2+-catalyzed recrystallization. On the basis of existing literature, we hypothesized that Fe2+-catalyzed recrystallization of goethite would not result in changes to individual particle morphology or interparticle interactions. To test this, we reacted nanoparticulate goethite with aqueous Fe2+ at pH 7.5 over 30 days and used transmission electron microscopy (TEM), cryogenic TEM, and 55Fe as an isotope tracer to observe changes in particle dimensions, aggregation, and isotopic composition over time. Over the course of 30 days, the goethite particles substantially recrystallized, and the particle dimensions changed anisotropically, resulting in a preferential increase in the mean particle width. The temporal changes in goethite morphology could not be completely explained by a single mineral-transformation mechanism but rather indicated that multiple transformation mechanisms occurred concurrently. Collectively, these results demonstrate that the morphology of goethite nanoparticles does change during recrystallization, which is an important step toward identifying the driving force(s) of recrystallization.

Original languageEnglish (US)
Pages (from-to)7315-7324
Number of pages10
JournalEnvironmental Science and Technology
Volume50
Issue number14
DOIs
StatePublished - Jul 19 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry

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