Application of phase-pure nickel phosphide nanoparticles as cathode catalysts for hydrogen production in microbial electrolysis cells

Transition metal phosphide catalysts such as nickel phosphide (Ni₂P) have shown excellent activities for the hydrogen evolution reaction, but they have primarily been studied in strongly acidic or alkaline electrolytes. In microbial electrolysis cells (MECs), however, the electrolyte is usually a neutral pH to support the bacteria. Carbon-supported phase-pure Ni₂P nanoparticle catalysts (Ni₂P/C) were synthesized using solution-phase methods and their performance was compared to Pt/C and Ni/C catalysts in MECs. The Ni₂P/C produced a similar quantity of hydrogen over a 24 h cycle (0.29 ± 0.04 L-H₂/L-reactor) as that obtained using Pt/C (0.32 ± 0.03 L-H₂/L) or Ni/C (0.29 ± 0.02 L-H₂/L). The mass normalized current density of the Ni₂P/C was 14 times higher than that of the Ni/C, and the Ni₂P/C exhibited stable performance over 11 days. Ni₂P/C may therefore be a useful alternative to Pt/C or other Ni-based catalysts in MECs due to its chemical stability over time.