Asphaltene - Silica interactions in aqueous solutions

Direct force measurements combined with electrokinetic studies

Thomas Abraham, D. Christendat, K. Karan, Z. Xu, J. Masliyah

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

An atomic force microscope (AFM) was used to study the interaction between asphaltenes and silica surfaces in aqueous solutions directly. Electrokinetic measurements were performed on similar systems to complement the AFM results. Asphaltene -silica interactions in aqueous solutions exhibited a time-dependent characteristic. A repulsive force component developed with increasing sample incubation time, suggesting molecular rearrangements at the asphaltenewater interface. Upon the addition of 1.0 mM KC1, the repulsive force was suppressed, and the measured force became overall attractive, implying an electrostatic nature for this repulsive force. An increase of the solution pH in the same system eliminated the attractive force regime through the development of a stronger repulsive force component. The increase in the range and magnitude of the asphaltene -silica interaction with increasing solution pH clearly indicates the presence of pH-dependent ionizable groups on the asphaltene surface. The measured longrange force can be very well accounted for by the Poisson - Boltzmann (PB) equation using a constant Stern layer potential boundary condition. The fitted Stern layer potentials of asphaltene surfaces (ψas) became more negative with increasing pH. In the case of asphaltenes at high solution pH values, a satisfactory agreement was obtained between the fitted Stern layer potential based on the AFM force measurements and the electrokinetic potential measured using the electrophoresis method. The swelling/stretching of surface asphaltene molecules at high solution pH and the sensitivity of such stretched layers to added salt were also evident from the force-distance data. The measured adhesion force correlated well with the long-range force behavior.

Original languageEnglish (US)
Pages (from-to)2170-2177
Number of pages8
JournalIndustrial and Engineering Chemistry Research
Volume41
Issue number9
DOIs
StatePublished - May 1 2002

Fingerprint

Force measurement
Silicon Dioxide
Silica
Asphaltenes
Microscopes
Boltzmann equation
Electrophoresis
Stretching
Swelling
asphaltene
Electrostatics
Adhesion
Salts
Boundary conditions
Molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

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abstract = "An atomic force microscope (AFM) was used to study the interaction between asphaltenes and silica surfaces in aqueous solutions directly. Electrokinetic measurements were performed on similar systems to complement the AFM results. Asphaltene -silica interactions in aqueous solutions exhibited a time-dependent characteristic. A repulsive force component developed with increasing sample incubation time, suggesting molecular rearrangements at the asphaltenewater interface. Upon the addition of 1.0 mM KC1, the repulsive force was suppressed, and the measured force became overall attractive, implying an electrostatic nature for this repulsive force. An increase of the solution pH in the same system eliminated the attractive force regime through the development of a stronger repulsive force component. The increase in the range and magnitude of the asphaltene -silica interaction with increasing solution pH clearly indicates the presence of pH-dependent ionizable groups on the asphaltene surface. The measured longrange force can be very well accounted for by the Poisson - Boltzmann (PB) equation using a constant Stern layer potential boundary condition. The fitted Stern layer potentials of asphaltene surfaces (ψas) became more negative with increasing pH. In the case of asphaltenes at high solution pH values, a satisfactory agreement was obtained between the fitted Stern layer potential based on the AFM force measurements and the electrokinetic potential measured using the electrophoresis method. The swelling/stretching of surface asphaltene molecules at high solution pH and the sensitivity of such stretched layers to added salt were also evident from the force-distance data. The measured adhesion force correlated well with the long-range force behavior.",
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Asphaltene - Silica interactions in aqueous solutions : Direct force measurements combined with electrokinetic studies. / Abraham, Thomas; Christendat, D.; Karan, K.; Xu, Z.; Masliyah, J.

In: Industrial and Engineering Chemistry Research, Vol. 41, No. 9, 01.05.2002, p. 2170-2177.

Research output: Contribution to journalArticle

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AU - Masliyah, J.

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