Assembly of gold nanowires by sedimentation from suspension: Experiments and simulation

Derek A. Triplett, Lisa M. Quimby, Benjamin D. Smith, Darimar Hernández Rodríguez, Sarah K. St. Angelo, Pedro González, Christine D. Keating, Kristen A. Fichthorn

Research output: Contribution to journalArticlepeer-review

15 Scopus citations


We investigated the ordering of gold nanowires that settled from an aqueous suspension onto a glass substrate due to gravity. The nanowires, ca. 300 nm in cross-sectional diameter and ca. 2, 4, or 7 μm in length, were coated with 2-mercaptoethanesulfonic acid to provide electrostatic repulsion and prevent aggregation. The layer of nanowires in direct contact with the substrate was examined from below using optical microscopy and found to exhibit smectic-like ordering. The extent of smectic ordering depended on nanowire length, with the shortest (2 μm) nanowires exhibiting the best ordering. To understand the assembly in this system, we used canonical Monte Carlo simulations to model the two-dimensional ordering of the nanowires on a substrate. We accounted for van der Waals and electrostatic interactions between the nanowires. The simulations reproduced the experimental trends and showed that roughness at the ends of the nanowires, which locally increased electrostatic repulsion, is critical to correctly predicting the experimentally observed smectic ordering.

Original languageEnglish (US)
Pages (from-to)7346-7355
Number of pages10
JournalJournal of Physical Chemistry C
Issue number16
StatePublished - Apr 29 2010

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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