ASSOCIATED SOLUTION MODEL FOR COMPOUND-FORMING LIQUID METAL MIXTURES.

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Abstract

An Associated Solution Model is presented for calculating the temperature and composition derivatives of the Gibbs energy for a binary compound-forming mixture. The model is an extension and generalization of the Sommer Associates Model. Expressions for calculating the enthalpy of mixing and the Darken stability function are given. The procedure is outlined for calculating any order temperature or composition derivative of the Gibbs energy. Examples of the functional form of the equations are given with parameters from the magnesium-tin system.

Original languageEnglish (US)
Pages (from-to)72-79
Number of pages8
JournalZeitschrift fuer Metallkunde/Materials Research and Advanced Techniques
Volume77
Issue number2
Publication statusPublished - Feb 1 1986

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All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Metals and Alloys
  • Materials Chemistry

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