Avoiding cross-linking in iron-polyphosphazene metallo-polymers

Ross J. Davidson, Eric W. Ainscough, Andrew M. Brodie, Mark R. Waterland, Harry R. Allcock, Mark D. Hindenlang, Guy N.L. Jameson

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Two new polyphosphazene ligands containing 1,10-phenanthrolin-2-olate (L1) and 2,2-bipyridine-6-olate moieties (L2) with 5,5-di-tert-butylbiphenyl-2,2-bis(olate) co-substituents were synthesised and then reacted with Fe(Pyridine)4(NCS)2. Variable temperature Mössbauer and electronic absorbance spectroscopies were used to establish the physical behaviour of the new iron-polyphosphazenes. By attaching two bidentate ligands to a geminal phosphorus atom a pseudo tetradentate ligand can be formed that prevents cross-linking when iron is coordinated to the polyphosphazene.

Original languageEnglish (US)
Pages (from-to)1-3
Number of pages3
JournalInorganic Chemistry Communications
Volume51
DOIs
StatePublished - Jan 1 2015

Fingerprint

Polymers
Iron
Ligands
iron
ligands
polymers
Pyridine
Phosphorus
phosphorus
pyridines
Spectroscopy
Atoms
electronics
spectroscopy
atoms
poly(phosphazene)
Temperature
temperature
pyridine

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Davidson, R. J., Ainscough, E. W., Brodie, A. M., Waterland, M. R., Allcock, H. R., Hindenlang, M. D., & Jameson, G. N. L. (2015). Avoiding cross-linking in iron-polyphosphazene metallo-polymers. Inorganic Chemistry Communications, 51, 1-3. https://doi.org/10.1016/j.inoche.2014.10.011
Davidson, Ross J. ; Ainscough, Eric W. ; Brodie, Andrew M. ; Waterland, Mark R. ; Allcock, Harry R. ; Hindenlang, Mark D. ; Jameson, Guy N.L. / Avoiding cross-linking in iron-polyphosphazene metallo-polymers. In: Inorganic Chemistry Communications. 2015 ; Vol. 51. pp. 1-3.
@article{8ecef31cde064702951afceb5b75a92d,
title = "Avoiding cross-linking in iron-polyphosphazene metallo-polymers",
abstract = "Two new polyphosphazene ligands containing 1,10-phenanthrolin-2-olate (L1) and 2,2-bipyridine-6-olate moieties (L2) with 5,5-di-tert-butylbiphenyl-2,2-bis(olate) co-substituents were synthesised and then reacted with Fe(Pyridine)4(NCS)2. Variable temperature M{\"o}ssbauer and electronic absorbance spectroscopies were used to establish the physical behaviour of the new iron-polyphosphazenes. By attaching two bidentate ligands to a geminal phosphorus atom a pseudo tetradentate ligand can be formed that prevents cross-linking when iron is coordinated to the polyphosphazene.",
author = "Davidson, {Ross J.} and Ainscough, {Eric W.} and Brodie, {Andrew M.} and Waterland, {Mark R.} and Allcock, {Harry R.} and Hindenlang, {Mark D.} and Jameson, {Guy N.L.}",
year = "2015",
month = "1",
day = "1",
doi = "10.1016/j.inoche.2014.10.011",
language = "English (US)",
volume = "51",
pages = "1--3",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier BV",

}

Davidson, RJ, Ainscough, EW, Brodie, AM, Waterland, MR, Allcock, HR, Hindenlang, MD & Jameson, GNL 2015, 'Avoiding cross-linking in iron-polyphosphazene metallo-polymers', Inorganic Chemistry Communications, vol. 51, pp. 1-3. https://doi.org/10.1016/j.inoche.2014.10.011

Avoiding cross-linking in iron-polyphosphazene metallo-polymers. / Davidson, Ross J.; Ainscough, Eric W.; Brodie, Andrew M.; Waterland, Mark R.; Allcock, Harry R.; Hindenlang, Mark D.; Jameson, Guy N.L.

In: Inorganic Chemistry Communications, Vol. 51, 01.01.2015, p. 1-3.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Avoiding cross-linking in iron-polyphosphazene metallo-polymers

AU - Davidson, Ross J.

AU - Ainscough, Eric W.

AU - Brodie, Andrew M.

AU - Waterland, Mark R.

AU - Allcock, Harry R.

AU - Hindenlang, Mark D.

AU - Jameson, Guy N.L.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - Two new polyphosphazene ligands containing 1,10-phenanthrolin-2-olate (L1) and 2,2-bipyridine-6-olate moieties (L2) with 5,5-di-tert-butylbiphenyl-2,2-bis(olate) co-substituents were synthesised and then reacted with Fe(Pyridine)4(NCS)2. Variable temperature Mössbauer and electronic absorbance spectroscopies were used to establish the physical behaviour of the new iron-polyphosphazenes. By attaching two bidentate ligands to a geminal phosphorus atom a pseudo tetradentate ligand can be formed that prevents cross-linking when iron is coordinated to the polyphosphazene.

AB - Two new polyphosphazene ligands containing 1,10-phenanthrolin-2-olate (L1) and 2,2-bipyridine-6-olate moieties (L2) with 5,5-di-tert-butylbiphenyl-2,2-bis(olate) co-substituents were synthesised and then reacted with Fe(Pyridine)4(NCS)2. Variable temperature Mössbauer and electronic absorbance spectroscopies were used to establish the physical behaviour of the new iron-polyphosphazenes. By attaching two bidentate ligands to a geminal phosphorus atom a pseudo tetradentate ligand can be formed that prevents cross-linking when iron is coordinated to the polyphosphazene.

UR - http://www.scopus.com/inward/record.url?scp=84910080644&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84910080644&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2014.10.011

DO - 10.1016/j.inoche.2014.10.011

M3 - Article

VL - 51

SP - 1

EP - 3

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -