Band-gap nonlinearity in perovskite structured solid solutions

Soonil Lee, Roni D. Levi, Weiguo Qu, Sung Chan Lee, Clive A. Randall

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Compositional effects on optical band-gap energy using end members of ABO3 perovskites have been investigated through an optical absorption with a UV-spectroscopy. Three examples are selected, namely, BaTiO3 - CaTiO3, BaTiO3 - BaZrO3, and SrTiO 3 - BaZrO3 solid solutions. To understand the role of high temperature phase equilibria on the band-gap compositional trends, structural and microscopy data were determined. In simple systems such as Si-Ge, the nonlinear variations in band gap with composition is usually associated with the effect of the local lattice relaxations and provides a parabolic dependence, often referred to as the "bowing" phenomena. In the case of perovskite solutions, the cases are more complex, and a modified Vegard's law is introduced to account for the trends. This has to be considered in relation to high temperature phase formation where incomplete solid solutions and two-phase regions exist. In addition to high temperature phases, low temperature displacive phase transitions and complex nonstoichiometry also perturb the band-gap variation in perovskite oxide materials.

Original languageEnglish (US)
Article number023523
JournalJournal of Applied Physics
Volume107
Issue number2
DOIs
StatePublished - Feb 8 2010

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solid solutions
nonlinearity
trends
perovskites
optical absorption
microscopy
oxides
spectroscopy

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

Lee, Soonil ; Levi, Roni D. ; Qu, Weiguo ; Lee, Sung Chan ; Randall, Clive A. / Band-gap nonlinearity in perovskite structured solid solutions. In: Journal of Applied Physics. 2010 ; Vol. 107, No. 2.
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Band-gap nonlinearity in perovskite structured solid solutions. / Lee, Soonil; Levi, Roni D.; Qu, Weiguo; Lee, Sung Chan; Randall, Clive A.

In: Journal of Applied Physics, Vol. 107, No. 2, 023523, 08.02.2010.

Research output: Contribution to journalArticle

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