Bicontinuous phase in diblock copolymer melts with added homopolymer

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

We compute in the strong-segregation regime the phase diagram of A-B diblock copolymer with added B homopolymer to see if the bicontinuous phase can be stabilized by adding homopolymers. Our work is motivated by the results of Ajdari and Leibler, who showed using a bending expansion that a single copolymer bilayer in excess homopolymer is unstable to Gaussian bends if the copolymers are sufficiently asymmetric. Our methods, which are not limited to a bending expansion, determine the region of homopolymer concentration and copolymer asymmetry for which a bicontinuous phase might be stable.

Original languageEnglish (US)
Pages (from-to)2404-2411
Number of pages8
JournalMacromolecules
Volume29
Issue number7
DOIs
StatePublished - Mar 25 1996

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Bicontinuous phase in diblock copolymer melts with added homopolymer'. Together they form a unique fingerprint.

  • Cite this