Bis(1-methyl-1H-imidazole-kN3)[N,N′-o-phenyl- enebis(pyridine-2-carbox-amido)-k4 N]manganese(II)

Zaki N. Zahran, Nan Xu, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, [Mn(C18H12N4O2)(C4H6N2)2], belongs to the family of 1,2-bis-(pyridine-2-carboxamido)benzene (H2bpb) ligated metal complexes. The manganese center is octa-hedrally coordinated by a bpb ligand and two axial 1-methyl-imidazole mol-ecules. The axial N - Mn - N group is bent with a bond angle of 151.79 (7)°.

Original languageEnglish (US)
Pages (from-to)m75
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number1
DOIs
StatePublished - Dec 1 2008

Fingerprint

Coordination Complexes
Manganese
Metal complexes
Benzene
imidazoles
Pyridine
manganese
pyridines
Ligands
benzene
ligands
metals
imidazole
pyridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Bis(1-methyl-1H-imidazole-kN3)[N,N′-o-phenyl- enebis(pyridine-2-carbox-amido)-k4 N]manganese(II)",
abstract = "The title compound, [Mn(C18H12N4O2)(C4H6N2)2], belongs to the family of 1,2-bis-(pyridine-2-carboxamido)benzene (H2bpb) ligated metal complexes. The manganese center is octa-hedrally coordinated by a bpb ligand and two axial 1-methyl-imidazole mol-ecules. The axial N - Mn - N group is bent with a bond angle of 151.79 (7)°.",
author = "Zahran, {Zaki N.} and Nan Xu and Powell, {Douglas R.} and Richter-Addo, {George B.}",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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Bis(1-methyl-1H-imidazole-kN3)[N,N′-o-phenyl- enebis(pyridine-2-carbox-amido)-k4 N]manganese(II). / Zahran, Zaki N.; Xu, Nan; Powell, Douglas R.; Richter-Addo, George B.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 1, 01.12.2008, p. m75.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Bis(1-methyl-1H-imidazole-kN3)[N,N′-o-phenyl- enebis(pyridine-2-carbox-amido)-k4 N]manganese(II)

AU - Zahran, Zaki N.

AU - Xu, Nan

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2008/12/1

Y1 - 2008/12/1

N2 - The title compound, [Mn(C18H12N4O2)(C4H6N2)2], belongs to the family of 1,2-bis-(pyridine-2-carboxamido)benzene (H2bpb) ligated metal complexes. The manganese center is octa-hedrally coordinated by a bpb ligand and two axial 1-methyl-imidazole mol-ecules. The axial N - Mn - N group is bent with a bond angle of 151.79 (7)°.

AB - The title compound, [Mn(C18H12N4O2)(C4H6N2)2], belongs to the family of 1,2-bis-(pyridine-2-carboxamido)benzene (H2bpb) ligated metal complexes. The manganese center is octa-hedrally coordinated by a bpb ligand and two axial 1-methyl-imidazole mol-ecules. The axial N - Mn - N group is bent with a bond angle of 151.79 (7)°.

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