Bismuth niobate thin films for dielectric energy storage applications

Dixiong Wang, Michael B. Clark, Susan E. Trolier-McKinstry

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Low-temperature processed bismuth niobate (BNO) thin films were explored in this work as a potential candidate for high-energy density capacitors. The BNO samples were fabricated by the chemical solution deposition method followed by a series of ultraviolet (UV) exposure and heat treatments. A UV treatment prior to the final pyrolysis step was found to be useful in eliminating bound carbon. X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) demonstrated that the residual carbon could be effectively removed at 350°C after UV exposure. Following a heat treatment at 450°C, the energy storage density of the BNO thin film reached 39 J/cm3 with an efficiency of 72%. Furthermore, 350°C and 375°C treated BNO samples showed high-temperature stability such that the efficiencies of the films remained above 97% up to 150°C at 10 kHz under 1 MV/cm applied field.

Original languageEnglish (US)
Pages (from-to)3443-3451
Number of pages9
JournalJournal of the American Ceramic Society
Volume101
Issue number8
DOIs
StatePublished - Aug 1 2018

Fingerprint

Bismuth
bismuth
Energy storage
Thin films
Carbon
Heat treatment
carbon
pyrolysis
X-ray spectroscopy
Pyrolysis
Capacitors
X ray photoelectron spectroscopy
spectroscopy
Spectroscopy
Ions
Temperature
energy storage
ion
energy
exposure

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Geology
  • Geochemistry and Petrology
  • Materials Chemistry

Cite this

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abstract = "Low-temperature processed bismuth niobate (BNO) thin films were explored in this work as a potential candidate for high-energy density capacitors. The BNO samples were fabricated by the chemical solution deposition method followed by a series of ultraviolet (UV) exposure and heat treatments. A UV treatment prior to the final pyrolysis step was found to be useful in eliminating bound carbon. X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) demonstrated that the residual carbon could be effectively removed at 350°C after UV exposure. Following a heat treatment at 450°C, the energy storage density of the BNO thin film reached 39 J/cm3 with an efficiency of 72{\%}. Furthermore, 350°C and 375°C treated BNO samples showed high-temperature stability such that the efficiencies of the films remained above 97{\%} up to 150°C at 10 kHz under 1 MV/cm applied field.",
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Bismuth niobate thin films for dielectric energy storage applications. / Wang, Dixiong; Clark, Michael B.; Trolier-McKinstry, Susan E.

In: Journal of the American Ceramic Society, Vol. 101, No. 8, 01.08.2018, p. 3443-3451.

Research output: Contribution to journalArticle

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AU - Wang, Dixiong

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