Block architecture influence on the structure and mechanical performance of drawn polyurethane elastomers

Borja Fernández-d'Arlas, Marian Corcuera, James Patrick Runt, Arantxa Eceiza

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The macromolecular orientation of some polyurethane elastomers can led to materials with varied mechanical properties. These properties are dependant on the molecular structure of both hard and soft segmants. Some natural biopolymers such as spider silk exhibit superb mechanical properties, characterised by their great toughness. Synthetic polyurethane (PU) copolymers also endow great toughness but lack silk's stiffness and strength. The aim of this work was to elucidate the role of segment block architectural features that influence PU stiffness and strength after cold drawing. For this purpose PUs with varied soft segment character, crystalline versus rubbery, as well as with different hard segment chemistries, 4,4'-diphenylmethane diisocyanate/1,4-butanediol versus 1,6-hexamethylene diisocyanate/1,4-butanediol, were synthesised by a two-step polymerisation method. We found that the architecture of both block segments has a dramatic influence on drawn PU mechanical performance, in which PUs with crystallisable soft segments and crystalline hard segments are shown to have a greater impact on developing stiffer and stronger materials.

Original languageEnglish (US)
Pages (from-to)1278-1287
Number of pages10
JournalPolymer International
Volume63
Issue number7
DOIs
StatePublished - 2014

Fingerprint

Elastomers
Polyurethanes
Silk
Toughness
Stiffness
Crystalline materials
Mechanical properties
Biopolymers
Molecular structure
Copolymers
Polymerization
1,4-butanediol

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Cite this

Fernández-d'Arlas, Borja ; Corcuera, Marian ; Runt, James Patrick ; Eceiza, Arantxa. / Block architecture influence on the structure and mechanical performance of drawn polyurethane elastomers. In: Polymer International. 2014 ; Vol. 63, No. 7. pp. 1278-1287.
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Block architecture influence on the structure and mechanical performance of drawn polyurethane elastomers. / Fernández-d'Arlas, Borja; Corcuera, Marian; Runt, James Patrick; Eceiza, Arantxa.

In: Polymer International, Vol. 63, No. 7, 2014, p. 1278-1287.

Research output: Contribution to journalArticle

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