Bonding in Nitrosylated Iron-Sulfur Clusters

Shen-shu Sung, Anthony R. Butler, Christopher Glidewell, Roald Hoffmann

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

The electronic structure of several binuclear and tetranuclear Fe clusters with bridging S or SH units and terminal nitrosyl ligands is analyzed. The computations point to the antibonding nature of the lowest unoccupied orbitals of these molecules, indicative of potential disruption of the clusters on reduction.

Original languageEnglish (US)
Pages (from-to)3856-3859
Number of pages4
JournalInorganic chemistry
Volume24
Issue number23
DOIs
StatePublished - Nov 1 1985

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Sulfur
Electronic structure
sulfur
Iron
Ligands
iron
Molecules
electronic structure
orbitals
ligands
molecules

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Sung, S., Butler, A. R., Glidewell, C., & Hoffmann, R. (1985). Bonding in Nitrosylated Iron-Sulfur Clusters. Inorganic chemistry, 24(23), 3856-3859. https://doi.org/10.1021/ic00217a030
Sung, Shen-shu ; Butler, Anthony R. ; Glidewell, Christopher ; Hoffmann, Roald. / Bonding in Nitrosylated Iron-Sulfur Clusters. In: Inorganic chemistry. 1985 ; Vol. 24, No. 23. pp. 3856-3859.
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Sung, S, Butler, AR, Glidewell, C & Hoffmann, R 1985, 'Bonding in Nitrosylated Iron-Sulfur Clusters', Inorganic chemistry, vol. 24, no. 23, pp. 3856-3859. https://doi.org/10.1021/ic00217a030

Bonding in Nitrosylated Iron-Sulfur Clusters. / Sung, Shen-shu; Butler, Anthony R.; Glidewell, Christopher; Hoffmann, Roald.

In: Inorganic chemistry, Vol. 24, No. 23, 01.11.1985, p. 3856-3859.

Research output: Contribution to journalArticle

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Sung S, Butler AR, Glidewell C, Hoffmann R. Bonding in Nitrosylated Iron-Sulfur Clusters. Inorganic chemistry. 1985 Nov 1;24(23):3856-3859. https://doi.org/10.1021/ic00217a030