Bottom-up synthesis of vertically oriented two-dimensional materials

R. A. Vilá, K. Momeni, Q. Wang, B. M. Bersch, N. Lu, M. J. Kim, L. Q. Chen, J. A. Robinson

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Understanding nucleation and growth of two-dimensional (2D) and layered materials is a challenging topic due to the complex van der Waals interactions between layers and substrate. The morphology of 2D materials is known vary depending on experimental conditions. For the case of MoS2, the morphology has been shown to vary from rounded (molybdenum rich) domains to equilateral triangular (sulfur rich) domains. These different morphologies can result in drastically different properties, which can be exploited for applications in catalytic reactions, digital electronics, optoelectronics, and energy storage. Powder vaporization (PV) synthesis of molybdenum disulfide (MoS2) can yield vertical domains, however, these domains are often ignored when the morphology evolution of MoS2 is discussed, thereby completely omitting a major part of the impact of the Mo:S ratio to the growth mode of MoS2 during PV. Combining experimental and numerical simulation methods, we reveal a vertical-to-horizontal growth mode transition for MoS2 that occurs in the presence of a molybdenum oxide partial pressure gradient. Transmission electron microscopy reveals that the growth of vertical MoS2 results from initial seeding of single crystalline molybdenum dioxide, followed by sulfurization from the substrate upward to form vertically oriented MoS2 domains.

Original languageEnglish (US)
Article number041003
Journal2D Materials
Volume3
Issue number4
DOIs
StatePublished - Oct 7 2016

Fingerprint

Molybdenum
synthesis
Vaporization
Powders
molybdenum
Molybdenum oxide
molybdenum disulfides
Substrates
Pressure gradient
molybdenum oxides
Sulfur
digital electronics
Partial pressure
Optoelectronic devices
Energy storage
energy storage
inoculation
dioxides
Nucleation
Electronic equipment

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Vilá, R. A., Momeni, K., Wang, Q., Bersch, B. M., Lu, N., Kim, M. J., ... Robinson, J. A. (2016). Bottom-up synthesis of vertically oriented two-dimensional materials. 2D Materials, 3(4), [041003]. https://doi.org/10.1088/2053-1583/3/4/041003
Vilá, R. A. ; Momeni, K. ; Wang, Q. ; Bersch, B. M. ; Lu, N. ; Kim, M. J. ; Chen, L. Q. ; Robinson, J. A. / Bottom-up synthesis of vertically oriented two-dimensional materials. In: 2D Materials. 2016 ; Vol. 3, No. 4.
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Bottom-up synthesis of vertically oriented two-dimensional materials. / Vilá, R. A.; Momeni, K.; Wang, Q.; Bersch, B. M.; Lu, N.; Kim, M. J.; Chen, L. Q.; Robinson, J. A.

In: 2D Materials, Vol. 3, No. 4, 041003, 07.10.2016.

Research output: Contribution to journalArticle

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Vilá RA, Momeni K, Wang Q, Bersch BM, Lu N, Kim MJ et al. Bottom-up synthesis of vertically oriented two-dimensional materials. 2D Materials. 2016 Oct 7;3(4). 041003. https://doi.org/10.1088/2053-1583/3/4/041003