Catalytic transfer hydrogenolysis of organosolv lignin using B-containing FeNi alloyed catalysts

Yagya N. Regmi, Jeffrey K. Mann, James R. McBride, Jingming Tao, Craig E. Barnes, Nicole Labbé, Stephen C. Chmely

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

In this work, FeB, NiB, and FeNiB nanomaterials were examined as catalysts for catalytic transfer hydrogenolysis (CTH) using supercritical ethanol (sc-EtOH) as the hydrogen donor and reaction solvent. The earth-abundant alloys were synthesized using simple aqueous chemical reductions and characterized using ICP-OES, XRD, and STEM-EDS. Using acetophenone to model the desired catalytic reactivity, FeNiB was identified as having superior reactivity (74% conversion) and selectivity for complete deoxygenation to ethylbenzene (84%) when compared to the monometallic materials. Given its high reactivity and selectivity for deoxygenation over ring saturation, FeNiB was screened as a lignin valorization catalyst. FeNiB mediates deoxygenation of aliphatic hydroxyl and carbonyls in organosolv lignin via CTH in sc-EtOH. A combination of gel permeation chromatography, GC/MS, and NMR spectroscopy was used to demonstrate the production of a slate of monomeric phenols with intact deoxygenated aliphatic side chains. In total, these results highlight the utility of CTH for the valorization of biorefinery-relevant lignin using an inexpensive, earth-abundant catalyst material and a green solvent system that can be directly derived from the polysaccharide fraction of lignocellulosic biomass.

Original languageEnglish (US)
Pages (from-to)190-195
Number of pages6
JournalCatalysis Today
Volume302
DOIs
StatePublished - Mar 15 2018

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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