catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate

Shaun O. Sommerer, Barry L. Westcott, Alan John Jircitano, Khalil A. Abboud

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) Å, and N-Ag-O 69.35 (9)o.

Original languageEnglish (US)
Pages (from-to)1426-1428
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number6
DOIs
StatePublished - Jun 15 1996

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Ketones
Silver
Anions
Ions
Ligands
Atoms

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

@article{8fe25345579f46b7ae8b8ecc55cbf1a6,
title = "catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate",
abstract = "The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) {\AA}, and N-Ag-O 69.35 (9)o.",
author = "Sommerer, {Shaun O.} and Westcott, {Barry L.} and Jircitano, {Alan John} and Abboud, {Khalil A.}",
year = "1996",
month = "6",
day = "15",
doi = "10.1107/S0108270196001503",
language = "English (US)",
volume = "52",
pages = "1426--1428",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "6",

}

catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate. / Sommerer, Shaun O.; Westcott, Barry L.; Jircitano, Alan John; Abboud, Khalil A.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 6, 15.06.1996, p. 1426-1428.

Research output: Contribution to journalArticle

TY - JOUR

T1 - catena-poly[silver-μ-(di-2-pyridyl ketone)-N,O:N′,O] tetrafluoroborate

AU - Sommerer, Shaun O.

AU - Westcott, Barry L.

AU - Jircitano, Alan John

AU - Abboud, Khalil A.

PY - 1996/6/15

Y1 - 1996/6/15

N2 - The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) Å, and N-Ag-O 69.35 (9)o.

AB - The title complex, [Ag(C11H8N2O)]+ n.n(BF4)-, contains polymeric [silver(di-2-pyridyl ketone)]+n zigzag chains, counterbalanced by BF-4 anions. The Ag atoms reside on inversion centers, the di-2-pyridyl ketone ligands lie with their carbonyl groups along crystallographic twofold axes, and the BF-4 ions also reside on inversion centers (and are disordered). The AgN2O2 moiety is precisely planar, with Ag-N 2.180 (3) and Ag-O 2.552 (1) Å, and N-Ag-O 69.35 (9)o.

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U2 - 10.1107/S0108270196001503

DO - 10.1107/S0108270196001503

M3 - Article

VL - 52

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EP - 1428

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 6

ER -