Ceramic coating for corrosion (c3) resistance of nuclear fuel cladding

Ece Alat, Arthur Thompson Motta, Robert J. Comstock, Jonna M. Partezana, Douglas Edward Wolfe

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

In an attempt to develop a nuclear fuel cladding that is more tolerant to loss-of-coolant-accidents (LOCA), ceramic coatings were deposited onto a ZIRLO™ 1 1ZIRLO is a trademark of Westinghouse Electric Co. substrate by cathodic arc physical vapor deposition (CA-PVD). The coatings consisted of either Ti 1-x Al x N or TiN ceramic monolithic layers with a titanium bond coating layer as the interlayer between the ceramic coating and the ZIRLO™ substrate to improve coating adhesion. Several coating deposition trials were performed investigating the effects of bond coating thickness (200-800nm), ceramic coating thickness (4, 8 and 12μm), substrate surface roughness prior to deposition, and select coating deposition processing parameters, such as nitrogen partial pressure and substrate bias, in order to optimize the coating durability in a corrosion environment. Corrosion tests were performed in static pure water at 360°C and saturation pressure (18.7MPa) for 3days. The optimized nitride-based ceramic coatings survived the autoclave test exposure showing very low weight gain of 1-5mg/dm 2 compared to the uncoated ZIRLO™ samples which showed an average weight gain of 14.4mg/dm 2 . Post-corrosion exposure analytical characterization showed that aluminum depletion occurred in the TiAlN coated samples during the autoclave corrosion test, which led to the formation of the boehmite phase that degraded the corrosion durability of some of the TiAlN samples. However, by eliminating the aluminum content and depositing TiN, the boehmite phase was prevented from forming. Best results in TiAlN coated samples were obtained with 600nm Ti bond coating thickness, 12μm coating thickness and 0.25μm substrate surface roughness (E14). Results are discussed in terms of the capability of TiN and Ti 1-x Al x N coatings to improve the high temperature corrosion resistance and oxidation resistance of zirconium alloy cladding.

Original languageEnglish (US)
Pages (from-to)133-143
Number of pages11
JournalSurface and Coatings Technology
Volume281
DOIs
StatePublished - Nov 15 2015

Fingerprint

Nuclear fuel cladding
ceramic coatings
Ceramic coatings
nuclear fuels
corrosion resistance
Corrosion
coatings
Coatings
Substrates
corrosion tests
corrosion
autoclaves
Autoclaves
Aluminum
durability
surface roughness
Durability
Surface roughness
loss of coolant
zirconium alloys

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

@article{3638558b49bb417fad330a9e6b5c786c,
title = "Ceramic coating for corrosion (c3) resistance of nuclear fuel cladding",
abstract = "In an attempt to develop a nuclear fuel cladding that is more tolerant to loss-of-coolant-accidents (LOCA), ceramic coatings were deposited onto a ZIRLO™ 1 1ZIRLO is a trademark of Westinghouse Electric Co. substrate by cathodic arc physical vapor deposition (CA-PVD). The coatings consisted of either Ti 1-x Al x N or TiN ceramic monolithic layers with a titanium bond coating layer as the interlayer between the ceramic coating and the ZIRLO™ substrate to improve coating adhesion. Several coating deposition trials were performed investigating the effects of bond coating thickness (200-800nm), ceramic coating thickness (4, 8 and 12μm), substrate surface roughness prior to deposition, and select coating deposition processing parameters, such as nitrogen partial pressure and substrate bias, in order to optimize the coating durability in a corrosion environment. Corrosion tests were performed in static pure water at 360°C and saturation pressure (18.7MPa) for 3days. The optimized nitride-based ceramic coatings survived the autoclave test exposure showing very low weight gain of 1-5mg/dm 2 compared to the uncoated ZIRLO™ samples which showed an average weight gain of 14.4mg/dm 2 . Post-corrosion exposure analytical characterization showed that aluminum depletion occurred in the TiAlN coated samples during the autoclave corrosion test, which led to the formation of the boehmite phase that degraded the corrosion durability of some of the TiAlN samples. However, by eliminating the aluminum content and depositing TiN, the boehmite phase was prevented from forming. Best results in TiAlN coated samples were obtained with 600nm Ti bond coating thickness, 12μm coating thickness and 0.25μm substrate surface roughness (E14). Results are discussed in terms of the capability of TiN and Ti 1-x Al x N coatings to improve the high temperature corrosion resistance and oxidation resistance of zirconium alloy cladding.",
author = "Ece Alat and Motta, {Arthur Thompson} and Comstock, {Robert J.} and Partezana, {Jonna M.} and Wolfe, {Douglas Edward}",
year = "2015",
month = "11",
day = "15",
doi = "10.1016/j.surfcoat.2015.08.062",
language = "English (US)",
volume = "281",
pages = "133--143",
journal = "Surface and Coatings Technology",
issn = "0257-8972",
publisher = "Elsevier",

}

Ceramic coating for corrosion (c3) resistance of nuclear fuel cladding. / Alat, Ece; Motta, Arthur Thompson; Comstock, Robert J.; Partezana, Jonna M.; Wolfe, Douglas Edward.

In: Surface and Coatings Technology, Vol. 281, 15.11.2015, p. 133-143.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Ceramic coating for corrosion (c3) resistance of nuclear fuel cladding

AU - Alat, Ece

AU - Motta, Arthur Thompson

AU - Comstock, Robert J.

AU - Partezana, Jonna M.

AU - Wolfe, Douglas Edward

PY - 2015/11/15

Y1 - 2015/11/15

N2 - In an attempt to develop a nuclear fuel cladding that is more tolerant to loss-of-coolant-accidents (LOCA), ceramic coatings were deposited onto a ZIRLO™ 1 1ZIRLO is a trademark of Westinghouse Electric Co. substrate by cathodic arc physical vapor deposition (CA-PVD). The coatings consisted of either Ti 1-x Al x N or TiN ceramic monolithic layers with a titanium bond coating layer as the interlayer between the ceramic coating and the ZIRLO™ substrate to improve coating adhesion. Several coating deposition trials were performed investigating the effects of bond coating thickness (200-800nm), ceramic coating thickness (4, 8 and 12μm), substrate surface roughness prior to deposition, and select coating deposition processing parameters, such as nitrogen partial pressure and substrate bias, in order to optimize the coating durability in a corrosion environment. Corrosion tests were performed in static pure water at 360°C and saturation pressure (18.7MPa) for 3days. The optimized nitride-based ceramic coatings survived the autoclave test exposure showing very low weight gain of 1-5mg/dm 2 compared to the uncoated ZIRLO™ samples which showed an average weight gain of 14.4mg/dm 2 . Post-corrosion exposure analytical characterization showed that aluminum depletion occurred in the TiAlN coated samples during the autoclave corrosion test, which led to the formation of the boehmite phase that degraded the corrosion durability of some of the TiAlN samples. However, by eliminating the aluminum content and depositing TiN, the boehmite phase was prevented from forming. Best results in TiAlN coated samples were obtained with 600nm Ti bond coating thickness, 12μm coating thickness and 0.25μm substrate surface roughness (E14). Results are discussed in terms of the capability of TiN and Ti 1-x Al x N coatings to improve the high temperature corrosion resistance and oxidation resistance of zirconium alloy cladding.

AB - In an attempt to develop a nuclear fuel cladding that is more tolerant to loss-of-coolant-accidents (LOCA), ceramic coatings were deposited onto a ZIRLO™ 1 1ZIRLO is a trademark of Westinghouse Electric Co. substrate by cathodic arc physical vapor deposition (CA-PVD). The coatings consisted of either Ti 1-x Al x N or TiN ceramic monolithic layers with a titanium bond coating layer as the interlayer between the ceramic coating and the ZIRLO™ substrate to improve coating adhesion. Several coating deposition trials were performed investigating the effects of bond coating thickness (200-800nm), ceramic coating thickness (4, 8 and 12μm), substrate surface roughness prior to deposition, and select coating deposition processing parameters, such as nitrogen partial pressure and substrate bias, in order to optimize the coating durability in a corrosion environment. Corrosion tests were performed in static pure water at 360°C and saturation pressure (18.7MPa) for 3days. The optimized nitride-based ceramic coatings survived the autoclave test exposure showing very low weight gain of 1-5mg/dm 2 compared to the uncoated ZIRLO™ samples which showed an average weight gain of 14.4mg/dm 2 . Post-corrosion exposure analytical characterization showed that aluminum depletion occurred in the TiAlN coated samples during the autoclave corrosion test, which led to the formation of the boehmite phase that degraded the corrosion durability of some of the TiAlN samples. However, by eliminating the aluminum content and depositing TiN, the boehmite phase was prevented from forming. Best results in TiAlN coated samples were obtained with 600nm Ti bond coating thickness, 12μm coating thickness and 0.25μm substrate surface roughness (E14). Results are discussed in terms of the capability of TiN and Ti 1-x Al x N coatings to improve the high temperature corrosion resistance and oxidation resistance of zirconium alloy cladding.

UR - http://www.scopus.com/inward/record.url?scp=84947087595&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84947087595&partnerID=8YFLogxK

U2 - 10.1016/j.surfcoat.2015.08.062

DO - 10.1016/j.surfcoat.2015.08.062

M3 - Article

AN - SCOPUS:84947087595

VL - 281

SP - 133

EP - 143

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

SN - 0257-8972

ER -