Characteristics of nitrogen release from synthetic zeolite Na-P1 occluding NH4NO3

Man Park, Jong Su Kim, Choong Lyeal Choi, Jang Eok Kim, Nam Ho Heo, Sridhar Komarneni, Jyung Choi

Research output: Contribution to journalArticle

17 Scopus citations

Abstract

Zeolites can accommodate a considerable amount of occluded salt such as NH4NO3, which can serve as a good source of slow-release plant nutrient. This study evaluates the kinetics of ion release from NH 4NO3-occluded Na-P1 (N-NaP) using a simulated soil solution and deionized water as leaching solutions. The patterns of ion releases were examined as a function of leaching time under both static and continuous-flow conditions for more than one month. Releases of both NH 4+ and NO3- from N-NaP were found to be slow and steady under both the above conditions. The soil solution affected the release of NH4+ and NO3- differently, while deionized water released nearly the same equivalents of these ions. This clearly indicates that ion release from salt-occluded zeolite involves two different reactions, cation exchange and dissolution. The kinetics of ion release from occluded NH4NO3 under static condition was best described by the standard Elovich model while the power function model best expressed these under continuous-flow condition. The initial ion release patterns under both conditions exhibited considerable deviation from the simulated models, probably as a result of the presence of hydrated occluded NH4NO3. Flow condition and the presence of electrolytes in leaching solution affected the release kinetics significantly. Release of occluded NH4NO3 was delayed by the presence of the NH 4NO3 coated on zeolite crystals. These results indicate that the ion release property of occluded salt could be predicted and controlled. This study clearly shows that NH4NO3-occluded zeolites could be developed as slow release fertilizers.

Original languageEnglish (US)
Pages (from-to)44-50
Number of pages7
JournalJournal of Controlled Release
Volume106
Issue number1-2
DOIs
StatePublished - Aug 18 2005

All Science Journal Classification (ASJC) codes

  • Pharmaceutical Science

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