Characterization and Comparison of Fast Pyrolysis Bio-oils from Pinewood, Rapeseed Cake, and Wheat Straw Using 13C NMR and Comprehensive GC × GC

Leila Negahdar, Arturo Gonzalez-Quiroga, Daria Otyuskaya, Hilal E. Toraman, Li Liu, Johann T.B.H. Jastrzebski, Kevin M. Van Geem, Guy B. Marin, Joris W. Thybaut, Bert M. Weckhuysen

Research output: Contribution to journalArticle

48 Scopus citations

Abstract

Fast pyrolysis bio-oils are feasible energy carriers and a potential source of chemicals. Detailed characterization of bio-oils is essential to further develop its potential use. In this study, quantitative 13C nuclear magnetic resonance (13C NMR) combined with comprehensive two-dimensional gas chromatography (GC × GC) was used to characterize fast pyrolysis bio-oils originated from pinewood, wheat straw, and rapeseed cake. The combination of both techniques provided new information on the chemical composition of bio-oils for further upgrading. 13C NMR analysis indicated that pinewood-based bio-oil contained mostly methoxy/hydroxyl (≈30%) and carbohydrate (≈27%) carbons; wheat straw bio-oil showed to have high amount of alkyl (≈35%) and aromatic (≈30%) carbons, while rapeseed cake-based bio-oil had great portions of alkyl carbons (≈82%). More than 200 compounds were identified and quantified using GC × GC coupled to a flame ionization detector (FID) and a time of flight mass spectrometer (TOF-MS). Nonaromatics were the most abundant and comprised about 50% of the total mass of compounds identified and quantified via GC × GC. In addition, this analytical approach allowed the quantification of high value-added phenolic compounds, as well as of low molecular weight carboxylic acids and aldehydes, which exacerbate the unstable and corrosive character of the bio-oil.

Original languageEnglish (US)
Pages (from-to)4974-4985
Number of pages12
JournalACS Sustainable Chemistry and Engineering
Volume4
Issue number9
DOIs
StatePublished - Sep 6 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

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    Negahdar, L., Gonzalez-Quiroga, A., Otyuskaya, D., Toraman, H. E., Liu, L., Jastrzebski, J. T. B. H., Van Geem, K. M., Marin, G. B., Thybaut, J. W., & Weckhuysen, B. M. (2016). Characterization and Comparison of Fast Pyrolysis Bio-oils from Pinewood, Rapeseed Cake, and Wheat Straw Using 13C NMR and Comprehensive GC × GC. ACS Sustainable Chemistry and Engineering, 4(9), 4974-4985. https://doi.org/10.1021/acssuschemeng.6b01329