Characterization of condensed-phase chemical reactions of rdx-based propellants

E. Boyer, Y. C. Lu, K. K. Kuo

Research output: Contribution to conferencePaperpeer-review

Abstract

A microprobe mass spectrometer was used to measure decomposition products from the subsurface region of XM39 and M43 RDX-based propellants. The microprobe was inserted into a hole drilled axially in the centerline of each propellant sample. Gaseous species released in the subsurface region were collected in the cavity and were sucked into the probe and analyzed. Tests were conducted in Ar at 1 and 3 atm, with a CO2 laser external heat flux of 100, 200, and 300 W/cm2. An insignificant amount of solid-phase decomposition products was detected for M43, and only a very minute amount of OST was detected from XM39 at very low heat flux conditions. At the time of burn through, the major species detected had masses of 30, 28,44, and 27 amu, believed to be CH2O, H2CN, N2O, and HCN. These products suggest the RDX decomposition pathway to form CH2O and N2O is more dominant for the condensed-phase reactions at the operating conditions studied. The binders of these two propellants showed relatively inactive behavior under the conditions tested.

Original languageEnglish (US)
DOIs
StatePublished - Jan 1 1995
Event31st Joint Propulsion Conference and Exhibit, 1995 - San Diego, United States
Duration: Jul 10 1995Jul 12 1995

Other

Other31st Joint Propulsion Conference and Exhibit, 1995
CountryUnited States
CitySan Diego
Period7/10/957/12/95

All Science Journal Classification (ASJC) codes

  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering
  • Mechanical Engineering
  • Control and Systems Engineering
  • Aerospace Engineering

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