Characterization of Polycyciic Aromatic Compounds on Surfaces Using Ion-Beam-Induced Desorption and Multiphoton Resonance Ionization

D. M. Hrubowchak, M. H. Ervin, Nicholas Winograd

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Multiphoton resonance ionization (MPRI) has been combined with ion-beam-induced desorption to examine polycyclic aromatic compounds (PAC’s) present on surfaces. The results show that it is possible to obtain extremely high-quality mass spectra of these compounds with subfemtomole sensitivity limits. Although the degree of ionization selectivity of atomic species is much lower than for MPRI of molecules, we show that it is possible to control the degree of photofragmentation by varying the laser intensity. Spectra obtained by MPRI, by nonresonant multiphoton ionization (MPI), and directly by secondary ion mass spectrometry (SIMS) are quantitatively compared. For pyrene, the molecular ion signal is more than 10 times larger for MPRI than for MPI and more than 100 times larger than with SIMS. From the measured intensities, we estimate the fraction of pyrene molecular ions formed in the SIMS mode is on the order of 10−4. Finally, we demonstrate that mixtures of PAC’s are readily detected by examining a cocktail of codeposited benzo[a]pyrene, dlbenz[ac]-anthracene, triphenylene, and pyrene. In general, we propose that this approach is a powerful new method for detecting low concentrations of complex molecules adsorbed on surfaces.

Original languageEnglish (US)
Pages (from-to)225-232
Number of pages8
JournalAnalytical Chemistry
Volume63
Issue number3
DOIs
StatePublished - Feb 1 1991

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Aromatic compounds
Ion beams
Ionization
Desorption
Secondary ion mass spectrometry
Ions
Molecules
Benzo(a)pyrene
Lasers
pyrene

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

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title = "Characterization of Polycyciic Aromatic Compounds on Surfaces Using Ion-Beam-Induced Desorption and Multiphoton Resonance Ionization",
abstract = "Multiphoton resonance ionization (MPRI) has been combined with ion-beam-induced desorption to examine polycyclic aromatic compounds (PAC’s) present on surfaces. The results show that it is possible to obtain extremely high-quality mass spectra of these compounds with subfemtomole sensitivity limits. Although the degree of ionization selectivity of atomic species is much lower than for MPRI of molecules, we show that it is possible to control the degree of photofragmentation by varying the laser intensity. Spectra obtained by MPRI, by nonresonant multiphoton ionization (MPI), and directly by secondary ion mass spectrometry (SIMS) are quantitatively compared. For pyrene, the molecular ion signal is more than 10 times larger for MPRI than for MPI and more than 100 times larger than with SIMS. From the measured intensities, we estimate the fraction of pyrene molecular ions formed in the SIMS mode is on the order of 10−4. Finally, we demonstrate that mixtures of PAC’s are readily detected by examining a cocktail of codeposited benzo[a]pyrene, dlbenz[ac]-anthracene, triphenylene, and pyrene. In general, we propose that this approach is a powerful new method for detecting low concentrations of complex molecules adsorbed on surfaces.",
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Characterization of Polycyciic Aromatic Compounds on Surfaces Using Ion-Beam-Induced Desorption and Multiphoton Resonance Ionization. / Hrubowchak, D. M.; Ervin, M. H.; Winograd, Nicholas.

In: Analytical Chemistry, Vol. 63, No. 3, 01.02.1991, p. 225-232.

Research output: Contribution to journalArticle

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AB - Multiphoton resonance ionization (MPRI) has been combined with ion-beam-induced desorption to examine polycyclic aromatic compounds (PAC’s) present on surfaces. The results show that it is possible to obtain extremely high-quality mass spectra of these compounds with subfemtomole sensitivity limits. Although the degree of ionization selectivity of atomic species is much lower than for MPRI of molecules, we show that it is possible to control the degree of photofragmentation by varying the laser intensity. Spectra obtained by MPRI, by nonresonant multiphoton ionization (MPI), and directly by secondary ion mass spectrometry (SIMS) are quantitatively compared. For pyrene, the molecular ion signal is more than 10 times larger for MPRI than for MPI and more than 100 times larger than with SIMS. From the measured intensities, we estimate the fraction of pyrene molecular ions formed in the SIMS mode is on the order of 10−4. Finally, we demonstrate that mixtures of PAC’s are readily detected by examining a cocktail of codeposited benzo[a]pyrene, dlbenz[ac]-anthracene, triphenylene, and pyrene. In general, we propose that this approach is a powerful new method for detecting low concentrations of complex molecules adsorbed on surfaces.

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