CHEMICAL THEORY FOR THE THERMODYNAMICS OF LIQUID METAL SOLUTIONS.

Montgomery Meigs Alger, Charles A. Eckert

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Chemical theory is used to represent both positive and negative deviations from Raoult's law in compound-forming liquid metal mixtures. The Ideal Chemical Theory (ICT) and Simplified Chemical Physical Theory (SCPT) models are presented that express the Gibbs energy of mixing as a function of temperature and bulk composition. The ICT model assumes compounds and monomers for an ideal liquid mixture. The SCPT model assumes that physical interactions are based on the bulk solution composition. Analytical expressions for mixture enthalpy, heat capacity, and Darken Stability Function are used and expressed in terms of the model parameters.

Original languageEnglish (US)
Pages (from-to)253-266
Number of pages14
JournalHigh temperature science
Volume19
Issue number3
StatePublished - Jun 1984

Fingerprint

Liquid metals
Thermodynamics
Gibbs free energy
Chemical analysis
Specific heat
Enthalpy
Monomers
Liquids
Temperature

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

@article{723ad8f9004848c7886a13178686e357,
title = "CHEMICAL THEORY FOR THE THERMODYNAMICS OF LIQUID METAL SOLUTIONS.",
abstract = "Chemical theory is used to represent both positive and negative deviations from Raoult's law in compound-forming liquid metal mixtures. The Ideal Chemical Theory (ICT) and Simplified Chemical Physical Theory (SCPT) models are presented that express the Gibbs energy of mixing as a function of temperature and bulk composition. The ICT model assumes compounds and monomers for an ideal liquid mixture. The SCPT model assumes that physical interactions are based on the bulk solution composition. Analytical expressions for mixture enthalpy, heat capacity, and Darken Stability Function are used and expressed in terms of the model parameters.",
author = "Alger, {Montgomery Meigs} and Eckert, {Charles A.}",
year = "1984",
month = "6",
language = "English (US)",
volume = "19",
pages = "253--266",
journal = "High temperature science",
issn = "0018-1536",
number = "3",

}

CHEMICAL THEORY FOR THE THERMODYNAMICS OF LIQUID METAL SOLUTIONS. / Alger, Montgomery Meigs; Eckert, Charles A.

In: High temperature science, Vol. 19, No. 3, 06.1984, p. 253-266.

Research output: Contribution to journalArticle

TY - JOUR

T1 - CHEMICAL THEORY FOR THE THERMODYNAMICS OF LIQUID METAL SOLUTIONS.

AU - Alger, Montgomery Meigs

AU - Eckert, Charles A.

PY - 1984/6

Y1 - 1984/6

N2 - Chemical theory is used to represent both positive and negative deviations from Raoult's law in compound-forming liquid metal mixtures. The Ideal Chemical Theory (ICT) and Simplified Chemical Physical Theory (SCPT) models are presented that express the Gibbs energy of mixing as a function of temperature and bulk composition. The ICT model assumes compounds and monomers for an ideal liquid mixture. The SCPT model assumes that physical interactions are based on the bulk solution composition. Analytical expressions for mixture enthalpy, heat capacity, and Darken Stability Function are used and expressed in terms of the model parameters.

AB - Chemical theory is used to represent both positive and negative deviations from Raoult's law in compound-forming liquid metal mixtures. The Ideal Chemical Theory (ICT) and Simplified Chemical Physical Theory (SCPT) models are presented that express the Gibbs energy of mixing as a function of temperature and bulk composition. The ICT model assumes compounds and monomers for an ideal liquid mixture. The SCPT model assumes that physical interactions are based on the bulk solution composition. Analytical expressions for mixture enthalpy, heat capacity, and Darken Stability Function are used and expressed in terms of the model parameters.

UR - http://www.scopus.com/inward/record.url?scp=0021437141&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0021437141&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0021437141

VL - 19

SP - 253

EP - 266

JO - High temperature science

JF - High temperature science

SN - 0018-1536

IS - 3

ER -