Chloridonitrosyl[meso-5,10,15,20-tetrakis(ptolyl)porphyrinato- κ4 N,N′,N″,N‴]osmium(II) tetrahydrofuran tetrasolvate

Li Chen, Nan Xu, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticle

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Abstract

The title compound, [OsCl(NO)(C48H36N 4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.

Original languageEnglish (US)
Pages (from-to)m224
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number2
DOIs
StatePublished - Feb 1 2011

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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