CO 2 capture from flue gas using molecular basket sorbents with different supports

Dongxiang Wang, Xiaoxing Wang, Xiaoliang Ma, Chunshan Song

Research output: Contribution to journalConference article

Abstract

CO 2 capture and storage has attracted great interests in both fundamental research and practical application. Solid amine sorbent has been considered as one of the potential sorbents for CO 2 capture, which is typically prepared by immobilization of CO 2-philic polyethylenimine (PEI) or oligomer on a mesoporous material such as MCM-41, SBA-15, MCM-48, KIT-6 etc. In this paper, we report our current progress in improvement of the sorption performance of the molecular basket sorbent (MBS) by using 3-D hexagonal mesoporous silica material (HMS) with wormhole like structure for CO 2 capture from flue gas. The result showed that HMS-MBS with 50 wt% PEI loading achieved a CO 2 sorption capacity of 150 mg-CO 2/g-sorb, which is higher than those of MBS prepared by MCM-41 (90 mg-CO 2/g-sorb) and SBA-15 (140 mg-CO 2/g-sorb) with the same PEI loading, although the pore size and pore volume of HMS is quite similar to MCM-41. In addition, the highest CO 2 sorption capacity of 180 mg-CO 2/g-sorb was obtained by loading 65% PEI over HMS. The superior CO 2 sorption capacity of HMS-MBS could be attributed to the special pore structure of HMS, i.e., 3-D wormhole channel motif structure and large textural mesoporosity.

Original languageEnglish (US)
JournalACS National Meeting Book of Abstracts
StatePublished - Dec 1 2011
Event242nd ACS National Meeting and Exposition - Denver, CO, United States
Duration: Aug 28 2011Sep 1 2011

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Carbon Monoxide
Sorbents
Flue gases
Silica
Multicarrier modulation
Sorption
Silicon Dioxide
Polyethyleneimine
Mesoporous materials
Pore structure
Oligomers
Pore size
Amines

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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title = "CO 2 capture from flue gas using molecular basket sorbents with different supports",
abstract = "CO 2 capture and storage has attracted great interests in both fundamental research and practical application. Solid amine sorbent has been considered as one of the potential sorbents for CO 2 capture, which is typically prepared by immobilization of CO 2-philic polyethylenimine (PEI) or oligomer on a mesoporous material such as MCM-41, SBA-15, MCM-48, KIT-6 etc. In this paper, we report our current progress in improvement of the sorption performance of the molecular basket sorbent (MBS) by using 3-D hexagonal mesoporous silica material (HMS) with wormhole like structure for CO 2 capture from flue gas. The result showed that HMS-MBS with 50 wt{\%} PEI loading achieved a CO 2 sorption capacity of 150 mg-CO 2/g-sorb, which is higher than those of MBS prepared by MCM-41 (90 mg-CO 2/g-sorb) and SBA-15 (140 mg-CO 2/g-sorb) with the same PEI loading, although the pore size and pore volume of HMS is quite similar to MCM-41. In addition, the highest CO 2 sorption capacity of 180 mg-CO 2/g-sorb was obtained by loading 65{\%} PEI over HMS. The superior CO 2 sorption capacity of HMS-MBS could be attributed to the special pore structure of HMS, i.e., 3-D wormhole channel motif structure and large textural mesoporosity.",
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CO 2 capture from flue gas using molecular basket sorbents with different supports. / Wang, Dongxiang; Wang, Xiaoxing; Ma, Xiaoliang; Song, Chunshan.

In: ACS National Meeting Book of Abstracts, 01.12.2011.

Research output: Contribution to journalConference article

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AU - Wang, Dongxiang

AU - Wang, Xiaoxing

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AU - Song, Chunshan

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