Cobalt doping to influence the electrical conductivity of (Bi0.91Dy0.09)FeO3 ceramics

Julian Walker, Thorsten J.M. Bayer, Maja Makarovic, Tomaz Kos, Susan Trolier-McKinstry, Barbara Malic, Tadej Rojac

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Rare earth modified bismuth ferrites are of interest as lead-free multiferroics, however reliable methods for reducing the electrical conductivity are needed. In this study ceramics with composition (Bi0.91Dy0.09)FeO3 were doped with 0.2 mol% cobalt (Co) and the impedance spectra, high electric field hysteresis and leakage current were compared to undoped ceramics. In pristine ceramics Co addition increased the bulk conductivity of the material but removed a relaxation from the dielectric loss and modulus in the frequency range 100 Hz–1 MHz. The remanent polarization and peak-to-peak strain of both ceramics were 38 µC/cm2 and 0.15% respectively, but surprisingly Co doped ceramics exhibited lower electrical leakage at above-coercive fields. Significant changes in the loss, modulus and leakage current of undoped ceramics after poling suggested that de-trapped charge carriers play a dominant role in the conductivity of undoped ceramics after poling. This effect was reduced by Co doping.

Original languageEnglish (US)
Pages (from-to)126-129
Number of pages4
JournalMaterials Letters
Volume225
DOIs
StatePublished - Aug 15 2018

Fingerprint

Cobalt
cobalt
Doping (additives)
ceramics
electrical resistivity
Leakage currents
leakage
Bismuth
Remanence
Ferrites
Dielectric losses
Charge carriers
Rare earths
Hysteresis
Lead
Electric fields
conductivity
Electric Conductivity
dielectric loss
bismuth

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Walker, Julian ; Bayer, Thorsten J.M. ; Makarovic, Maja ; Kos, Tomaz ; Trolier-McKinstry, Susan ; Malic, Barbara ; Rojac, Tadej. / Cobalt doping to influence the electrical conductivity of (Bi0.91Dy0.09)FeO3 ceramics. In: Materials Letters. 2018 ; Vol. 225. pp. 126-129.
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Cobalt doping to influence the electrical conductivity of (Bi0.91Dy0.09)FeO3 ceramics. / Walker, Julian; Bayer, Thorsten J.M.; Makarovic, Maja; Kos, Tomaz; Trolier-McKinstry, Susan; Malic, Barbara; Rojac, Tadej.

In: Materials Letters, Vol. 225, 15.08.2018, p. 126-129.

Research output: Contribution to journalArticle

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AU - Walker, Julian

AU - Bayer, Thorsten J.M.

AU - Makarovic, Maja

AU - Kos, Tomaz

AU - Trolier-McKinstry, Susan

AU - Malic, Barbara

AU - Rojac, Tadej

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