Coherent raman spectroscopy of HCN complexes

G. A. Hopkins, M. Maroncelli, J. W. Nibler, T. R. Dyke

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

Photoacoustic Raman spectroscopy (PARS) is shown to be a sensitive technique for obtaining Raman spectra of hydrogen-bonded complexes in the gas phase. Coherent anti-Stokes Raman spectroscopy (CARS) provides analogous spectra in supersonic expansions. The effective resolution is higher in the latter case due to the cooling and collision-free conditions in the jet. The ability to "tune" complex size by changing expansion conditions is demonstrated in the case of HCN.

Original languageEnglish (US)
Pages (from-to)97-102
Number of pages6
JournalChemical Physics Letters
Volume114
Issue number1
DOIs
StatePublished - Feb 15 1985

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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