Coherent raman spectroscopy of HCN complexes

G. A. Hopkins, Mark Maroncelli, J. W. Nibler, T. R. Dyke

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Photoacoustic Raman spectroscopy (PARS) is shown to be a sensitive technique for obtaining Raman spectra of hydrogen-bonded complexes in the gas phase. Coherent anti-Stokes Raman spectroscopy (CARS) provides analogous spectra in supersonic expansions. The effective resolution is higher in the latter case due to the cooling and collision-free conditions in the jet. The ability to "tune" complex size by changing expansion conditions is demonstrated in the case of HCN.

Original languageEnglish (US)
Pages (from-to)97-102
Number of pages6
JournalChemical Physics Letters
Volume114
Issue number1
DOIs
StatePublished - Feb 15 1985

Fingerprint

Raman spectroscopy
Photoacoustic spectroscopy
photoacoustic spectroscopy
expansion
Raman scattering
Hydrogen
Gases
Raman spectra
vapor phases
Cooling
cooling
collisions
high resolution
hydrogen

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Hopkins, G. A. ; Maroncelli, Mark ; Nibler, J. W. ; Dyke, T. R. / Coherent raman spectroscopy of HCN complexes. In: Chemical Physics Letters. 1985 ; Vol. 114, No. 1. pp. 97-102.
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Coherent raman spectroscopy of HCN complexes. / Hopkins, G. A.; Maroncelli, Mark; Nibler, J. W.; Dyke, T. R.

In: Chemical Physics Letters, Vol. 114, No. 1, 15.02.1985, p. 97-102.

Research output: Contribution to journalArticle

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