Colouration by total internal reflection and interference at microscale concave interfaces

Amy E. Goodling, Sara Nagelberg, Bryan Kaehr, Caleb H. Meredith, Seong Ik Cheon, Ashley P. Saunders, Mathias Kolle, Lauren D. Zarzar

Research output: Contribution to journalLetter

4 Citations (Scopus)

Abstract

Many physical phenomena create colour: spectrally selective light absorption by pigments and dyes 1,2 , material-specific optical dispersion 3 and light interference 4–11 in micrometre-scale and nanometre-scale periodic structures 12–17 . In addition, scattering, diffraction and interference mechanisms are inherent to spherical droplets 18 , which contribute to atmospheric phenomena such as glories, coronas and rainbows 19 . Here we describe a previously unrecognized mechanism for creating iridescent structural colour with large angular spectral separation. Light travelling along different trajectories of total internal reflection at a concave optical interface can interfere to generate brilliant patterns of colour. The effect is generated at interfaces with dimensions that are orders of magnitude larger than the wavelength of visible light and is readily observed in systems as simple as water drops condensed on a transparent substrate. We also exploit this phenomenon in complex systems, including multiphase droplets, three-dimensional patterned polymer surfaces and solid microparticles, to create patterns of iridescent colour that are consistent with theoretical predictions. Such controllable structural colouration is straightforward to generate at microscale interfaces, so we expect that the design principles and predictive theory outlined here will be of interest both for fundamental exploration in optics and for application in functional colloidal inks and paints, displays and sensors.

Original languageEnglish (US)
Pages (from-to)523-527
Number of pages5
JournalNature
Volume566
Issue number7745
DOIs
StatePublished - Feb 28 2019

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Color
Light
Physical Phenomena
Ink
Paint
Polymers
Water

All Science Journal Classification (ASJC) codes

  • General

Cite this

Goodling, A. E., Nagelberg, S., Kaehr, B., Meredith, C. H., Cheon, S. I., Saunders, A. P., ... Zarzar, L. D. (2019). Colouration by total internal reflection and interference at microscale concave interfaces. Nature, 566(7745), 523-527. https://doi.org/10.1038/s41586-019-0946-4
Goodling, Amy E. ; Nagelberg, Sara ; Kaehr, Bryan ; Meredith, Caleb H. ; Cheon, Seong Ik ; Saunders, Ashley P. ; Kolle, Mathias ; Zarzar, Lauren D. / Colouration by total internal reflection and interference at microscale concave interfaces. In: Nature. 2019 ; Vol. 566, No. 7745. pp. 523-527.
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Goodling, AE, Nagelberg, S, Kaehr, B, Meredith, CH, Cheon, SI, Saunders, AP, Kolle, M & Zarzar, LD 2019, 'Colouration by total internal reflection and interference at microscale concave interfaces', Nature, vol. 566, no. 7745, pp. 523-527. https://doi.org/10.1038/s41586-019-0946-4

Colouration by total internal reflection and interference at microscale concave interfaces. / Goodling, Amy E.; Nagelberg, Sara; Kaehr, Bryan; Meredith, Caleb H.; Cheon, Seong Ik; Saunders, Ashley P.; Kolle, Mathias; Zarzar, Lauren D.

In: Nature, Vol. 566, No. 7745, 28.02.2019, p. 523-527.

Research output: Contribution to journalLetter

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AU - Nagelberg, Sara

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AU - Saunders, Ashley P.

AU - Kolle, Mathias

AU - Zarzar, Lauren D.

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Goodling AE, Nagelberg S, Kaehr B, Meredith CH, Cheon SI, Saunders AP et al. Colouration by total internal reflection and interference at microscale concave interfaces. Nature. 2019 Feb 28;566(7745):523-527. https://doi.org/10.1038/s41586-019-0946-4