Comparison of polylactide/nano-sized calcium carbonate and polylactide/montmorillonite composites: Reinforcing effects and toughening mechanisms

Long Jiang, Jinwen Zhang, Michael P. Wolcott

Research output: Contribution to journalArticle

303 Citations (Scopus)

Abstract

Semicrystalline polylactide (PLA) exhibits high tensile strength and modulus but very low strain-at-break and toughness. In this study, PLA nanocomposites with nano-sized precipitated calcium carbonate (NPCC) and organically modified montmorillonite (MMT) clay were prepared by melt extrusion. Morphologies, tensile mechanical properties, dynamic mechanical and rheological properties, polymer-nanoparticle interactions, and toughening mechanisms of the PLA/NPCC and PLA/MMT nanocomposites were compared. MMT and NPCC showed significantly different effects on the strength, modulus and elongation of the PLA nanocomposites. Different toughening mechanisms were first elucidated for the two types of nanocomposites based on the evidence from both macroscopic and microscopic observations. Under uniaxial tension, large quantities of microvoids were created in both PLA nanocomposites. The microvoids in PLA/NPCC caused massive crazing, while in PLA/MMT they resulted in shear yielding, particularly in the nanocomposite with 2.5 wt% MMT. The MMT stacks and platelets were found to be located between the microvoids in the extended specimens and prevented them from collapsing and coalescing.

Original languageEnglish (US)
Pages (from-to)7632-7644
Number of pages13
JournalPolymer
Volume48
Issue number26
DOIs
StatePublished - Dec 13 2007

Fingerprint

Bentonite
Calcium Carbonate
Toughening
Calcium carbonate
Clay minerals
Nanocomposites
Composite materials
Crazing
Platelets
Toughness
Extrusion
poly(lactide)
Elongation
Clay
Tensile strength
Elastic moduli
Nanoparticles
Mechanical properties
Polymers

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

@article{f368abbfd97242c2b99ed7abb9033b9a,
title = "Comparison of polylactide/nano-sized calcium carbonate and polylactide/montmorillonite composites: Reinforcing effects and toughening mechanisms",
abstract = "Semicrystalline polylactide (PLA) exhibits high tensile strength and modulus but very low strain-at-break and toughness. In this study, PLA nanocomposites with nano-sized precipitated calcium carbonate (NPCC) and organically modified montmorillonite (MMT) clay were prepared by melt extrusion. Morphologies, tensile mechanical properties, dynamic mechanical and rheological properties, polymer-nanoparticle interactions, and toughening mechanisms of the PLA/NPCC and PLA/MMT nanocomposites were compared. MMT and NPCC showed significantly different effects on the strength, modulus and elongation of the PLA nanocomposites. Different toughening mechanisms were first elucidated for the two types of nanocomposites based on the evidence from both macroscopic and microscopic observations. Under uniaxial tension, large quantities of microvoids were created in both PLA nanocomposites. The microvoids in PLA/NPCC caused massive crazing, while in PLA/MMT they resulted in shear yielding, particularly in the nanocomposite with 2.5 wt{\%} MMT. The MMT stacks and platelets were found to be located between the microvoids in the extended specimens and prevented them from collapsing and coalescing.",
author = "Long Jiang and Jinwen Zhang and Wolcott, {Michael P.}",
year = "2007",
month = "12",
day = "13",
doi = "10.1016/j.polymer.2007.11.001",
language = "English (US)",
volume = "48",
pages = "7632--7644",
journal = "Polymer",
issn = "0032-3861",
publisher = "Elsevier BV",
number = "26",

}

Comparison of polylactide/nano-sized calcium carbonate and polylactide/montmorillonite composites : Reinforcing effects and toughening mechanisms. / Jiang, Long; Zhang, Jinwen; Wolcott, Michael P.

In: Polymer, Vol. 48, No. 26, 13.12.2007, p. 7632-7644.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Comparison of polylactide/nano-sized calcium carbonate and polylactide/montmorillonite composites

T2 - Reinforcing effects and toughening mechanisms

AU - Jiang, Long

AU - Zhang, Jinwen

AU - Wolcott, Michael P.

PY - 2007/12/13

Y1 - 2007/12/13

N2 - Semicrystalline polylactide (PLA) exhibits high tensile strength and modulus but very low strain-at-break and toughness. In this study, PLA nanocomposites with nano-sized precipitated calcium carbonate (NPCC) and organically modified montmorillonite (MMT) clay were prepared by melt extrusion. Morphologies, tensile mechanical properties, dynamic mechanical and rheological properties, polymer-nanoparticle interactions, and toughening mechanisms of the PLA/NPCC and PLA/MMT nanocomposites were compared. MMT and NPCC showed significantly different effects on the strength, modulus and elongation of the PLA nanocomposites. Different toughening mechanisms were first elucidated for the two types of nanocomposites based on the evidence from both macroscopic and microscopic observations. Under uniaxial tension, large quantities of microvoids were created in both PLA nanocomposites. The microvoids in PLA/NPCC caused massive crazing, while in PLA/MMT they resulted in shear yielding, particularly in the nanocomposite with 2.5 wt% MMT. The MMT stacks and platelets were found to be located between the microvoids in the extended specimens and prevented them from collapsing and coalescing.

AB - Semicrystalline polylactide (PLA) exhibits high tensile strength and modulus but very low strain-at-break and toughness. In this study, PLA nanocomposites with nano-sized precipitated calcium carbonate (NPCC) and organically modified montmorillonite (MMT) clay were prepared by melt extrusion. Morphologies, tensile mechanical properties, dynamic mechanical and rheological properties, polymer-nanoparticle interactions, and toughening mechanisms of the PLA/NPCC and PLA/MMT nanocomposites were compared. MMT and NPCC showed significantly different effects on the strength, modulus and elongation of the PLA nanocomposites. Different toughening mechanisms were first elucidated for the two types of nanocomposites based on the evidence from both macroscopic and microscopic observations. Under uniaxial tension, large quantities of microvoids were created in both PLA nanocomposites. The microvoids in PLA/NPCC caused massive crazing, while in PLA/MMT they resulted in shear yielding, particularly in the nanocomposite with 2.5 wt% MMT. The MMT stacks and platelets were found to be located between the microvoids in the extended specimens and prevented them from collapsing and coalescing.

UR - http://www.scopus.com/inward/record.url?scp=36549038684&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=36549038684&partnerID=8YFLogxK

U2 - 10.1016/j.polymer.2007.11.001

DO - 10.1016/j.polymer.2007.11.001

M3 - Article

AN - SCOPUS:36549038684

VL - 48

SP - 7632

EP - 7644

JO - Polymer

JF - Polymer

SN - 0032-3861

IS - 26

ER -